Cellulase deactivation based kinetic modeling of enzymatic hydrolysis of steam-exploded wheat straw
文献类型:期刊论文
作者 | Zhang, Yu1,2![]() ![]() ![]() ![]() |
刊名 | bioresource technology
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出版日期 | 2010-11-01 |
卷号 | 101期号:21页码:8261-8266 |
关键词 | Cellulase kinetics Enzyme deactivation Mathematical model Enzymatic hydrolysis of cellulose Simulation and prediction |
ISSN号 | 0960-8524 |
产权排序 | [zhang, yu; xu, jing-liang; xu, hui-juan; yuan, zhen-hong; guo, ying] chinese acad sci, key lab renewable energy & gas hydrate, guangzhou inst energy convers, guangzhou 510640, peoples r china; [zhang, yu; guo, ying] chinese acad sci, grad univ, beijing 100049, peoples r china |
通讯作者 | yuanzh@ms.giec.ac.cn |
中文摘要 | applying mass action law and quasi-steady-state theory, two cellulase kinetic models namely eqs. (5) and (8) were developed on the basis of the first and second order reactions of enzyme deactivation, respectively. the two models are compared according to analysis of experimental data from enzymatic hydrolysis steam-exploded wheat straw. both simulation and prediction results show eq. (8) has much higher accuracy than eq. (5). analysis of initial hydrolysis rate is also in accordance with eq. (8) and against eq. (5). fitted values of k(2) (the rate constant of product formation), k(de2) (the rate constant of enzyme deactivation) and k(e) (the equilibrium constant) determined from eq. (8) are 0.4732 h(-1), 0.4011 l/(h g), and 16.8597 g/l, respectively. the higher the enzyme concentration is, the larger the deactivation rate. |
英文摘要 | applying mass action law and quasi-steady-state theory, two cellulase kinetic models namely eqs. (5) and (8) were developed on the basis of the first and second order reactions of enzyme deactivation, respectively. the two models are compared according to analysis of experimental data from enzymatic hydrolysis steam-exploded wheat straw. both simulation and prediction results show eq. (8) has much higher accuracy than eq. (5). analysis of initial hydrolysis rate is also in accordance with eq. (8) and against eq. (5). fitted values of k(2) (the rate constant of product formation), k(de2) (the rate constant of enzyme deactivation) and k(e) (the equilibrium constant) determined from eq. (8) are 0.4732 h(-1), 0.4011 l/(h g), and 16.8597 g/l, respectively. the higher the enzyme concentration is, the larger the deactivation rate. (c) 2010 elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
学科主题 | agriculture ; biotechnology & applied microbiology ; energy & fuels |
类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
关键词[WOS] | cotton gin waste ; induced inactivation ; corn stover ; optimization ; ethanol ; pretreatment ; reactor |
收录类别 | SCI |
资助信息 | chinese academy of sciences [kscx-yw-11-a3, kgcx2-yw-335, kscx2-yw-g-075-9]; national high technology research and development program of china (863 program) [2007aa05z406, 2009aa05z436] |
原文出处 | https://dx.doi.org/10.1016/j.biortech.2010.06.015 |
语种 | 英语 |
WOS记录号 | WOS:000280570900035 |
公开日期 | 2014-12-24 |
源URL | [http://ir.giec.ac.cn/handle/344007/8471] ![]() |
专题 | 中国科学院广州能源研究所 生物质能源生化转化实验室 |
作者单位 | 1.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Yu,Xu, Jing-Liang,Xu, Hui-Juan,et al. Cellulase deactivation based kinetic modeling of enzymatic hydrolysis of steam-exploded wheat straw[J]. bioresource technology,2010,101(21):8261-8266. |
APA | Zhang, Yu,Xu, Jing-Liang,Xu, Hui-Juan,Yuan, Zhen-Hong,&Guo, Ying.(2010).Cellulase deactivation based kinetic modeling of enzymatic hydrolysis of steam-exploded wheat straw.bioresource technology,101(21),8261-8266. |
MLA | Zhang, Yu,et al."Cellulase deactivation based kinetic modeling of enzymatic hydrolysis of steam-exploded wheat straw".bioresource technology 101.21(2010):8261-8266. |
入库方式: OAI收割
来源:广州能源研究所
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