Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H
文献类型：期刊论文
| 作者 | Li, Liang-Qun1,2,3; Li, Ming-Ming2; Chen, Dong2,3; Liu, Hao-Miao2,3; Geng, Hui-Chun2,3; Lin, Jun1; Qin, Hong-Bo2
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| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2014-10-22 |
| 卷号 | 55期号:43页码:5960-5962 |
| 关键词 | Stereoselective formal synthesis (+)-Dichroanone (+)-Taiwaniaquinone H Conjugate addition Reetz reagent |
| ISSN号 | 0040-4039 |
| 产权排序 | 第二 |
| 通讯作者 | Lin,J (reprint author),Yunnan Univ,Sch Chem Sci & Technol,Key Lab Med Chem Nat Resources,Minist Educ,Kunming 650091,Peoples R China. ; linjun@ynu.edu.cn ; qinhongbo@mail.kib.ac.cn |
| 英文摘要 | Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H has been achieved. Key step involved construction of all-carbon quaternary carbon by palladium-catalyzed conjugate addition of arylboronic acid to 3-methyl cyclohexenone. Furthermore, a new approach to build [6-5-6] tricyclic backbone via formyl introduction and subsequent aldol-type condensation was also explored. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TAIWANIA-CRYPTOMERIOIDES ; CONJUGATE ADDITION ; ARYLBORONIC ACIDS ; THUJA-STANDISHII ; EFFICIENT ROUTE ; DITERPENES ; BARK ; (+/-)-DICHROANONE ; (+/-)-TAIWANIAQUINOL-B ; CONSTRUCTION |
| 收录类别 | SCI ; IC |
| 资助信息 | National Natural Science Foundation of China [21372229]; Natural Science Foundation of Yunnan Province [2013FB064]; Program of 'One Hundred Talented People' |
| 语种 | 英语 |
| WOS记录号 | WOS:000343624300020 |
| 公开日期 | 2014-11-25 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/18391]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resources, Minist Educ, Kunming 650091, Peoples R China 2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Liang-Qun,Li, Ming-Ming,Chen, Dong,et al. Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H[J]. TETRAHEDRON LETTERS,2014,55(43):5960-5962. |
| APA | Li, Liang-Qun.,Li, Ming-Ming.,Chen, Dong.,Liu, Hao-Miao.,Geng, Hui-Chun.,...&Qin, Hong-Bo.(2014).Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H.TETRAHEDRON LETTERS,55(43),5960-5962. |
| MLA | Li, Liang-Qun,et al."Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H".TETRAHEDRON LETTERS 55.43(2014):5960-5962. |
入库方式： OAI收割
来源：昆明植物研究所
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