二甲醚和乙醇低压层流预混火焰的对比研究
文献类型：期刊论文
| 作者 | Yang Hao-Lin (杨浩林) ; Jiang Li-Qiao (蒋利桥); Wang Xiao-Han (汪小憨); Zhao Dai-Qing (赵黛青)
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| 刊名 | ACTA PHYSICO-CHIMICA SINICA
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| 出版日期 | 2010-01 |
| 卷号 | 26期号:1页码:6,23-28 |
| 关键词 | Synchrotron radiation Single-photon ionization Dimethyl ether Ethanol Premixed laminar flame PHOTOIONIZATION MASS-SPECTROMETRY FUEL-RICH OXIDATION CHEMISTRY KINETICS DME 同步辐射 单光子电离 二甲醚 乙醇 层流预混火焰 |
| ISSN号 | 1000-6818 |
| 其他题名 | Comparative Study of Dimethyl Ether and Ethanol Premixed Laminar Flames at Low Pressure |
| 产权排序 | [Gao Jian (高健); Zhao Dai-Qing (赵黛青); Wang Xiao-Han (汪小憨); Jiang Li-Qiao (蒋利桥); Yang Hao-Lin (杨浩林)] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China; [Yuan Tao (袁涛); Yang Jiu-Zhong (杨玖重)] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China; [Gao Jian (高健)] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 通讯作者 | Zhao, DQ (赵黛青)(reprint author), Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China. |
| 中文摘要 | Low pressure premixed laminar dimethyl ether (DME)/oxygen/argon and ethanol/oxygen/argon flames (equivalence ratio: 1.0) were studied by molecular-beam sampling mass spectrometry (MBMS) combined with the tunable synchrotron radiation photoionization technique. Combustion intermediates were identified by measuring photoionization efficiency (PEE) spectra, and the mole fraction profiles of these species at different flame positions were presented. Similarities and differences of main intermediate formation characteristics between the two flames were analyzed based on derived reaction mechanisms. Experimental results show that both flames contain the same intermediates such as CH3, CH4, C2H2, CH2O, CH2O, CH3OH, CH2=C=O, CH3CHO, and CH2CHOH. In the DME flame, the concentration of the C-2 species is much higher than that of the C-2 species, i.e., C-2 intermediates tend to form rather than C-2 intermediates in a DME flame. In addition, formaldehyde is the dominant C-1 species in each flame. The concentrations Of C-2 species like ethylene, acetaldehyde, acetylene, and ketene in the ethanol flame are remarkably higher than that found in the DME flame. 利用分子束质谱结合真空紫外同步辐射光电离技术对相同燃烧条件下的低压层流预混二甲醚/氧气/氩气和乙醇/氧气/氩气火焰进行研究. 通过测量光电离效率曲线, 识别了二甲醚和乙醇火焰的中间物种, 得到相应的火焰质谱;通过测量火焰中各物种在燃烧炉炉膛各位置的电离信号强度, 得到了各物种的摩尔分数分布曲线.结合两种燃料分子不同的化学结构及详细的燃烧化学反应机理, 分析了两火焰中间物种生成特性的异同. 研究结果表明:甲醛为两火焰中最主要的C1中间物种; 二甲醚火焰趋向于生成C1中间物种, C2物种摩尔分数较低;乙醇火焰中乙醛、乙烯、乙炔和乙烯酮等C2中间物种的摩尔分数明显高于二甲醚火焰中的值. |
| 学科主题 | Chemistry |
| 收录类别 | SCI ; CSCD |
| 资助信息 | The project was supported by the National Natural Science Foundation of China (50806079) and Natural Science Foundation of Guangdong Province,China (8151007006000014). |
| 原文出处 | https://dx.doi.org/10.3866/PKU.WHXB20091216 |
| 语种 | 中文 |
| 公开日期 | 2014-12-31 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/8531]  |
| 专题 | 中国科学院广州能源研究所 能源战略研究中心 |
| 推荐引用方式 GB/T 7714 | Yang Hao-Lin (杨浩林),Jiang Li-Qiao (蒋利桥),Wang Xiao-Han (汪小憨),等. 二甲醚和乙醇低压层流预混火焰的对比研究[J]. ACTA PHYSICO-CHIMICA SINICA,2010,26(1):6,23-28. |
| APA | Yang Hao-Lin ,Jiang Li-Qiao ,Wang Xiao-Han ,&Zhao Dai-Qing .(2010).二甲醚和乙醇低压层流预混火焰的对比研究.ACTA PHYSICO-CHIMICA SINICA,26(1),6,23-28. |
| MLA | Yang Hao-Lin ,et al."二甲醚和乙醇低压层流预混火焰的对比研究".ACTA PHYSICO-CHIMICA SINICA 26.1(2010):6,23-28. |
入库方式： OAI收割
来源：广州能源研究所
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