Vincamajorines A and B, monoterpenoid indole alkaloids with new carbon skeletons from Vinca major
文献类型：期刊论文
| 作者 | Zhang, Zhi-Jun1,2; Yang, Jing2,3 ; He, Juan2; Wu, Xing-De2; Shao, Li-Dong2; Li, Yan2; Huang, Sheng-Xiong2; Li, Rong-Tao1; Zhao, Qin-Shi2
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| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2014-11-19 |
| 卷号 | 55期号:47页码:6490-6494 |
| 关键词 | Vinca major Monoterpenoid indole alkaloids Quantum chemical calculations |
| ISSN号 | 0040-4039 |
| 产权排序 | 第一 |
| 通讯作者 | Li,RT (reprint author),Kunming Univ Sci & Technol,Fac Life Sci & Technol,Chenggong Campus,Kunming 650050,Yunnan,Peoples R China. ; rongtaolikm@163.com ; qinshizhao@mail.kib.ac.cn |
| 英文摘要 | Two new monoterpenoid indole alkaloids, vincamajorines A (1) and B (2), were isolated from Vinca major. Their structures were elucidated by means of 1D and 2D NMR, and HREIMS spectroscopic data. The relative and absolute configurations were deduced by comparing the experimental C-13 NMR, ECD spectra, and OR data with those theoretically calculated. Vincamajorine A (1) represents a new C-20 carbon skeleton arranged compactly in seven rings, and vincamajorine B(2) is an alkaloid with an unprecedented 6/5/7/5/6 pentacyclic ring system. A possible biosynthetic pathway was also proposed for the formation of 1 and 2. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry, Organic |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ALSTONIA-SCHOLARIS ; CHEMICAL-SHIFTS ; CHEMISTRY ; STEREOCHEMISTRY ; PROGRESS |
| 收录类别 | SCI ; IC |
| 资助信息 | National Natural Science Foundation of China [31320103919, 31300199]; National Key Basic Research Program of China [2014CB954100]; Key Research Program of the Chinese Academy of Sciences [KJZD-EW-L07]; Natural Science Foundation of Yunnan Province [2011FB101]; Western Light Project of the Chinese Academy of Sciences [292013312D11015] |
| 语种 | 英语 |
| WOS记录号 | WOS:000344825300027 |
| 公开日期 | 2015-01-20 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/18455]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Kunming Univ Sci & Technol, Fac Life Sci & Technol, Kunming 650050, Yunnan, Peoples R China 2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhi-Jun,Yang, Jing,He, Juan,et al. Vincamajorines A and B, monoterpenoid indole alkaloids with new carbon skeletons from Vinca major[J]. TETRAHEDRON LETTERS,2014,55(47):6490-6494. |
| APA | Zhang, Zhi-Jun.,Yang, Jing.,He, Juan.,Wu, Xing-De.,Shao, Li-Dong.,...&Zhao, Qin-Shi.(2014).Vincamajorines A and B, monoterpenoid indole alkaloids with new carbon skeletons from Vinca major.TETRAHEDRON LETTERS,55(47),6490-6494. |
| MLA | Zhang, Zhi-Jun,et al."Vincamajorines A and B, monoterpenoid indole alkaloids with new carbon skeletons from Vinca major".TETRAHEDRON LETTERS 55.47(2014):6490-6494. |
入库方式： OAI收割
来源：昆明植物研究所
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