Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0-14
文献类型：期刊论文
| 作者 | Tian, Jingqi ; Liu, Qian ; Asiri, Abdullah M. ; Sun,Xuping |
| 刊名 | journal of the american chemical society
 |
| 出版日期 | 2014 |
| 卷号 | 136期号:21页码:7587-7590 |
| 关键词 | ACTIVE EDGE SITES EVOLUTION REACTION H-2 PRODUCTION ELECTRONIC-STRUCTURE GENERATING HYDROGEN WATER CATALYSTS MOS2 CO ELECTROCATALYST |
| ISSN号 | 0002-7863 |
| 通讯作者 | sun,xp |
| 中文摘要 | in this communication, we report the topotactic fabrication of self-supported nanoporous cobalt phosphide nanowire arrays on carbon cloth (cop/cc) via low-temperature phosphidation of the corresponding co(oh)f/cc precursor. the cop/cc, as a robust integrated 3d hydrogen-evolving cathode, shows a low onset overpotential of 38 mv and a small tafel slope of si mv dec(-1), and it maintains its catalytic activity for at least 80 000 s in acidic media. it needs overpotentials (eta) of 67, 100, and 204 mv to attain current densities of 10, 20, and 100 ma cm(-2), respectively. additionally, this electrode offers excellent catalytic performance and durability under neutral and basic conditions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000336635400016 |
| 公开日期 | 2015-03-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50631]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tian, Jingqi,Liu, Qian,Asiri, Abdullah M.,et al. Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0-14[J]. journal of the american chemical society,2014,136(21):7587-7590. |
| APA | Tian, Jingqi,Liu, Qian,Asiri, Abdullah M.,&Sun,Xuping.(2014).Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0-14.journal of the american chemical society,136(21),7587-7590. |
| MLA | Tian, Jingqi,et al."Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0-14".journal of the american chemical society 136.21(2014):7587-7590. |
入库方式： OAI收割
来源：长春应用化学研究所
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