Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor
文献类型:期刊论文
作者 | Song, Xue-Zhi ; Song, Shu-Yan ; Zhao, Shu-Na ; hao,Zhao-Min ; Zhu,Min ; Meng,Xing ; Wu,Lan-Lan ; Zhang,Hong-Jie |
刊名 | advanced functional materials
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出版日期 | 2014 |
卷号 | 24期号:26页码:4034-4041 |
关键词 | STRUCTURED EU-MOF THERMAL-STABILITY NITRO EXPLOSIVES SMALL MOLECULES BUILDING UNITS SELECTIVE GAS SOLID-STATE POLYMERS SORPTION EXCHANGE |
ISSN号 | 1616-301x |
通讯作者 | song,xz |
中文摘要 | a sensor with a red-emission signal is successfully obtained by the solvothermal reaction of eu3+ and heterofunctional ligand bpydbh(2) (4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid), followed by terminal-ligand exchange in a single-crystal-to-single-crystal transformation. as a result of treatments both before and after the metal-organic framework formation, accessible lewis-base sites and coordinated water molecules are successfully anchored onto the host material, and they act as signal transmission media for the recognition of analytes at the molecular level. this is the first reported sensor based on a metal-organic framework (mof) with multi-responsive optical sensing properties. it is capable of sensing small organic molecules and inorganic ions, and unprecedentedly it can discriminate among the homologues and isomers of aliphatic alcohols as well as detect highly explosive 2,4,6-trinitrophenol (tnp) in water or in the vapor phase. this work highlights the practical application of luminescent mofs as sensors, and it paves the way toward other multi-responsive sensors by demonstrating the incorporation of various functional groups into a single framework. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000339565300002 |
公开日期 | 2015-03-16 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50652] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Song, Xue-Zhi,Song, Shu-Yan,Zhao, Shu-Na,et al. Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor[J]. advanced functional materials,2014,24(26):4034-4041. |
APA | Song, Xue-Zhi.,Song, Shu-Yan.,Zhao, Shu-Na.,hao,Zhao-Min.,Zhu,Min.,...&Zhang,Hong-Jie.(2014).Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor.advanced functional materials,24(26),4034-4041. |
MLA | Song, Xue-Zhi,et al."Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor".advanced functional materials 24.26(2014):4034-4041. |
入库方式: OAI收割
来源:长春应用化学研究所
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