中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Incorporating ATP into biomimetic catalysts for realizing exceptional enzymatic performance over a broad temperature range

文献类型:期刊论文

作者Lin, Youhui ; Huang, Yanyan ; Ren, Jinsong ; Qu,Xiaogang
刊名npg asia materials
出版日期2014
卷号6期号:4页码:295-304
关键词PEROXIDASE-LIKE ACTIVITY CERIUM OXIDE NANOPARTICLES GOLD NANOPARTICLES ARTIFICIAL ENZYMES PTPD-FE3O4 NANOPARTICLES HYDROGEN-PEROXIDE REDOX STATE GLUCOSE REDUCTION PHOSPHATE
ISSN号1884-4049
通讯作者ren,js
中文摘要there has been great interest in the development of artificial inorganic nanomaterials that mimic natural peroxidases. unfortunately, these nanomaterials usually possess relatively low catalytic activity and are generally considered to work effectively only within a narrow temperature range (for example, they are inactive at high temperatures). intriguingly, adenosine triphosphate (atp) is not only the ubiquitous energy currency of life, it is also known to form charge transfer complexes with aromatic molecules and to participate in free radical redox chemistry. inspired by its unique properties, for the first time, we reveal a novel catalytic role for atp and show that atp is an ideal boosting agent for markedly improving the catalytic activity of a peroxidase mimic over a broad temperature range and, more significantly, making it possible to achieve exceptionally efficient high-temperature catalytic reactions. these observations pave the way for identifying highly effective modulators that promote the overall performance of artificial enzymes.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000341623400006
公开日期2015-03-25
源URL[http://ir.ciac.jl.cn/handle/322003/50659]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Lin, Youhui,Huang, Yanyan,Ren, Jinsong,et al. Incorporating ATP into biomimetic catalysts for realizing exceptional enzymatic performance over a broad temperature range[J]. npg asia materials,2014,6(4):295-304.
APA Lin, Youhui,Huang, Yanyan,Ren, Jinsong,&Qu,Xiaogang.(2014).Incorporating ATP into biomimetic catalysts for realizing exceptional enzymatic performance over a broad temperature range.npg asia materials,6(4),295-304.
MLA Lin, Youhui,et al."Incorporating ATP into biomimetic catalysts for realizing exceptional enzymatic performance over a broad temperature range".npg asia materials 6.4(2014):295-304.

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来源:长春应用化学研究所

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