PdxCoy Nanoparticle/Carbon Nanofiber Composites with Enhanced Electrocatalytic Properties
文献类型：期刊论文
| 作者 | Liu, Dong ; Guo, Qiaohui ; Hou, Haoqing ; Niwa,Osamu ; You,Tianyan |
| 刊名 | acs catalysis
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:6页码:1825-1829 |
| 关键词 | ALCOHOL FUEL-CELLS OXYGEN REDUCTION FORMIC-ACID CARBON NANOTUBES MESOPOROUS CARBON METHANOL OXIDATION PD ELECTROOXIDATION CATALYSTS |
| ISSN号 | 2155-5435 |
| 通讯作者 | you,ty |
| 中文摘要 | novel bimetallic pdxcoy alloy nanoparticle (np)/carbon nanofiber (cnf) composites with superior electrocatalytic performances were successfully prepared by electrospinning pd and co precursors, i.e., pd(acac)2 and co(acac)(2), in polyacrylonitrile followed by a thermal treatment. uniform dispersion of pdxcoy nanoparticles in carbon nanofibers was achieved. chemical composition and size of the resulting pdxcoy nps, which showed a substantial effect on the electrocatalytic properties of pdxcoy/cnf nanocomposites, can be readily controlled by adjusting the feed ratio of metal precursors. in comparison with commercial pd/c and other state-of-the-art pd- or pt-based catalysts, pdxcoy/cnf nanocomposites prepared in this study exhibited much higher electrocatalytic activity and stability in formic acid and methanol oxidation reactions. this improved electrocatalytic performance is very attractive for fuel cell applications and can be attributed to the unique bimetallic pd co alloy formation, a modified electronic structure of pd in pdxcoy, as well as uniform dispersion and firm embedment of pdxcoy nps in cnf. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000337074700021 |
| 公开日期 | 2015-03-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50678]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu, Dong,Guo, Qiaohui,Hou, Haoqing,et al. PdxCoy Nanoparticle/Carbon Nanofiber Composites with Enhanced Electrocatalytic Properties[J]. acs catalysis,2014,4(6):1825-1829. |
| APA | Liu, Dong,Guo, Qiaohui,Hou, Haoqing,Niwa,Osamu,&You,Tianyan.(2014).PdxCoy Nanoparticle/Carbon Nanofiber Composites with Enhanced Electrocatalytic Properties.acs catalysis,4(6),1825-1829. |
| MLA | Liu, Dong,et al."PdxCoy Nanoparticle/Carbon Nanofiber Composites with Enhanced Electrocatalytic Properties".acs catalysis 4.6(2014):1825-1829. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。