Charge state-dependent catalytic activity of [Au-25(SC12H25)(18)] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide
文献类型：期刊论文
| 作者 | Lu, Yizhong ; Jiang, Yuanyuan ; Gao, Xiaohui ; Chen,Wei |
| 刊名 | chemical communications
 |
| 出版日期 | 2014 |
| 卷号 | 50期号:62页码:8464-8467 |
| 关键词 | CRYSTAL-STRUCTURE PROTECTED AU-25 AU CLUSTERS NANOPARTICLES MONODISPERSE CONVERSION OXIDATION |
| ISSN号 | 1359-7345 |
| 通讯作者 | chen,w |
| 中文摘要 | the electrochemical production of h2o2 from o-2 catalyzed by [au-25(sc12h25)(18)] was studied as a function of the charge state (-1, 0 and +1). maximum h2o2 production (similar to 90%) was obtained from the negatively charged clusters (au-25(-)) due to the efficient electron transfer from the anionic au-25(-) cluster into the lumo (pi*) of o-2. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000339228500002 |
| 公开日期 | 2015-03-30 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50740]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu, Yizhong,Jiang, Yuanyuan,Gao, Xiaohui,et al. Charge state-dependent catalytic activity of [Au-25(SC12H25)(18)] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide[J]. chemical communications,2014,50(62):8464-8467. |
| APA | Lu, Yizhong,Jiang, Yuanyuan,Gao, Xiaohui,&Chen,Wei.(2014).Charge state-dependent catalytic activity of [Au-25(SC12H25)(18)] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide.chemical communications,50(62),8464-8467. |
| MLA | Lu, Yizhong,et al."Charge state-dependent catalytic activity of [Au-25(SC12H25)(18)] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide".chemical communications 50.62(2014):8464-8467. |
入库方式： OAI收割
来源：长春应用化学研究所
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