Graphenized pencil lead fiber: Facile preparation and application in solid-phase microextraction
文献类型：期刊论文
| 作者 | Liu, Qian ; Cheng, Mengting ; Long, Yanmin ; Yu, Miao ; Wang, Thanh ; Jiang, Guibin |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2014 |
| 卷号 | 1325期号:1页码:1-7 |
| 关键词 | Solid-phase microextraction Pencil lead Graphene Chemical exfoliation Bisphenol |
| ISSN号 | 0021-9673 |
| 中文摘要 | Graphenized pencil lead fiber was facilely prepared by in situ chemical exfoliation of graphite in pencil lead fiber to few-layered graphene sheets via a one-pot, one-step pressurized oxidation reaction for the first time. This new fiber was characterized and demonstrated to be a highly efficient but low-cost solid-phase microextraction (SPME) fiber. The extraction performance of the fiber was evaluated with four bisphenol analogs [bisphenol A (BPA), bisphenol S (BPS), bisphenol AF (BPAF), and tetrabromobisphenol A (TBBPA)] as model analytes in direct SPME mode. Unlike commercially available fibers, the graphenized pencil lead fiber showed an excellent chemical stability in highly saline, acidic, alkaline and organic conditions due to its coating-free configuration. The fiber also showed a very long lifespan. Furthermore, high extraction efficiency and good selectivity for the analytes with a wide polarity range could be obtained due to the exceptional properties of graphene. The detection limits (LODs) for the analytes were in the range of 1.1-25 ng/L. The fiber was successfully applied in the analysis of tap water and effluent samples from a waste water treatment plant with spike recoveries ranging from 68.5 to 105.1%. Therefore, the graphenized pencil lead fiber provides a high performance, cheap, robust, and reliable tool for SPME. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000330256200001 |
| 公开日期 | 2015-03-24 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/9375]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu, Qian,Cheng, Mengting,Long, Yanmin,et al. Graphenized pencil lead fiber: Facile preparation and application in solid-phase microextraction[J]. JOURNAL OF CHROMATOGRAPHY A,2014,1325(1):1-7. |
| APA | Liu, Qian,Cheng, Mengting,Long, Yanmin,Yu, Miao,Wang, Thanh,&Jiang, Guibin.(2014).Graphenized pencil lead fiber: Facile preparation and application in solid-phase microextraction.JOURNAL OF CHROMATOGRAPHY A,1325(1),1-7. |
| MLA | Liu, Qian,et al."Graphenized pencil lead fiber: Facile preparation and application in solid-phase microextraction".JOURNAL OF CHROMATOGRAPHY A 1325.1(2014):1-7. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。