Synthesis of carbon-coated magnetic nanocomposite (Fe3O4@C) and its application for sulfonamide antibiotics removal from water
文献类型:期刊论文
作者 | Bao, Xiaolei ; Qiang, Zhimin ; Chang, Jih-Hsing ; Ben, Weiwei ; Qu, Jiuhui |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
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出版日期 | 2014 |
卷号 | 26期号:5页码:962-969 |
关键词 | magnetic nanocomposite carbon shell sulfonamides adsorption water |
ISSN号 | 1001-0742 |
中文摘要 | The occurrence of antibiotics in the environment has recently raised serious concerns regarding their potential threat to human health and aquatic ecosystem! A new magnetic nanocomposite, Fe3O4@C (Fe3O4 coated with carbon), was synthesized, characterized, and then applied to remove five commonly-used sulfonamides (SAs) from water. Due to its combinational merits of the outer functionalized carbon shell and the inner magnetite core, Fe3O4@C exhibited a high adsorption affinity for selected SAs and a fast magnetic separability. The adsorption kinetics of SAs on Fe3O4@C could be expressed by the pseudo second-order model. The adsorption isotherms were fitted well with the Dual-mode model, revealing that the adsorption process consisted of an initial partitioning stage and a subsequent hole-filling stage. Solution pH exerted a strong impact on the adsorption process with the maximum removal efficiencies (74% to 96%) obtained at pH 4.8 for all selected SAs. Electrostatic force and hydrogen bonding were two major driving forces for adsorption, and electron-donor-acceptor interactions may also make a certain contribution. Because the synthesized Fe3O4@C showed comprehensive advantages of high adsorptivity, fast magnetic separability, and prominent reusability, it has potential applications in water treatment. |
WOS记录号 | WOS:000335489400003 |
公开日期 | 2015-03-26 |
源URL | [http://ir.rcees.ac.cn/handle/311016/9607] ![]() |
专题 | 生态环境研究中心_环境水质学国家重点实验室 |
推荐引用方式 GB/T 7714 | Bao, Xiaolei,Qiang, Zhimin,Chang, Jih-Hsing,et al. Synthesis of carbon-coated magnetic nanocomposite (Fe3O4@C) and its application for sulfonamide antibiotics removal from water[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2014,26(5):962-969. |
APA | Bao, Xiaolei,Qiang, Zhimin,Chang, Jih-Hsing,Ben, Weiwei,&Qu, Jiuhui.(2014).Synthesis of carbon-coated magnetic nanocomposite (Fe3O4@C) and its application for sulfonamide antibiotics removal from water.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,26(5),962-969. |
MLA | Bao, Xiaolei,et al."Synthesis of carbon-coated magnetic nanocomposite (Fe3O4@C) and its application for sulfonamide antibiotics removal from water".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 26.5(2014):962-969. |
入库方式: OAI收割
来源:生态环境研究中心
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