Environmental behavior of benalaxyl and furalaxyl enantiomers in agricultural soils
文献类型:期刊论文
作者 | Qin, Fang ; Gao, Yong X. ; Guo, Bao Y. ; Xu, Peng ; Li, Jian Z. ; Wang, Hui L. |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES
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出版日期 | 2014 |
卷号 | 49期号:10页码:738-746 |
关键词 | Chiral fungicides enantioselective environmental behavior benalaxyl furalaxyl |
ISSN号 | 0360-1234 |
中文摘要 | The enantioselective environmental behavior of the chiral fungicides benalaxy and furalaxyl in agricultural soils in China was studied. Although sorption onto soils was non-enantioselective, the leaching of benalaxy and furalaxyl was enantioselective in soil columns. The concentrations of the S-enantiomers of both fungicides in the leachates were higher than the R-enantiomers. This can be attributed to enantioselective degradation of the two fungicides in the soil column. Enantioselective degradation of the two fungicides was verified by soil dissipation experiments, and the R-enantiomers degraded faster than the S-enantiomers in partial soils. The half-life was 27.7-57.8 days for S-benalaxyl, 20.4-53.3 days for R-benalaxyl, 19.3-49.5 days for S-furalaxyl and 11.434.7 days for R-furalaxyl. The degradation process of the two fungicide enantiomers followed the first-order kinetics (R-2 > 0.96). Compared to furalaxyl, benalaxyl degraded more slowly and degradation was less enantioselective. These results are attributed to the influence of soil physicochemical properties, soil microorganisms, and environmental factors. |
WOS记录号 | WOS:000340264900004 |
公开日期 | 2015-03-26 |
源URL | [http://ir.rcees.ac.cn/handle/311016/9661] ![]() |
专题 | 生态环境研究中心_中国科学院环境生物技术重点实验室 |
推荐引用方式 GB/T 7714 | Qin, Fang,Gao, Yong X.,Guo, Bao Y.,et al. Environmental behavior of benalaxyl and furalaxyl enantiomers in agricultural soils[J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES,2014,49(10):738-746. |
APA | Qin, Fang,Gao, Yong X.,Guo, Bao Y.,Xu, Peng,Li, Jian Z.,&Wang, Hui L..(2014).Environmental behavior of benalaxyl and furalaxyl enantiomers in agricultural soils.JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES,49(10),738-746. |
MLA | Qin, Fang,et al."Environmental behavior of benalaxyl and furalaxyl enantiomers in agricultural soils".JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES 49.10(2014):738-746. |
入库方式: OAI收割
来源:生态环境研究中心
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