Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media
文献类型:期刊论文
作者 | Cheng, L ; Dai, QG ; Li, H ; Wang, XY |
刊名 | CATALYSIS COMMUNICATIONS
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出版日期 | 2014 |
卷号 | 57页码:23—28 |
关键词 | VAPOR-PHASE HYDROGENATION PALLADIUM CATALYSTS CYCLOHEXANONE PRESSURE CARBON |
ISSN号 | 1566-7367 |
通讯作者 | wangxy@ecust.edu.cn |
英文摘要 | Pd/Al2O3 and Pd/SiO2 catalysts containing Pd nanoparticles in the size range of 3-13 nm were prepared and investigated in direct selective hydrogenation of phenol to cyclohexanone. Catalysts with 3 nm Pd nanoparticles present highly active and promoted the selective formation of cyclohexanone under atmospheric pressure of hydrogen in aqueous media without additives. Conversion of 99% and a selectivity higher than 99% were achieved within 3 h at 333 K. The generality of Pd/Al2O3 catalyst with 3 nm Pd nanoparticles for this reaction was demonstrated by selective hydrogenation of other hydroxylated aromatic compounds with similar performance. (C) 2014 Published by Elsevier B.V. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000343364200006 |
公开日期 | 2015-03-13 |
源URL | [http://ir.sinap.ac.cn/handle/331007/14173] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Cheng, L,Dai, QG,Li, H,et al. Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media[J]. CATALYSIS COMMUNICATIONS,2014,57:23—28. |
APA | Cheng, L,Dai, QG,Li, H,&Wang, XY.(2014).Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media.CATALYSIS COMMUNICATIONS,57,23—28. |
MLA | Cheng, L,et al."Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media".CATALYSIS COMMUNICATIONS 57(2014):23—28. |
入库方式: OAI收割
来源:上海应用物理研究所
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