Hydrogen-Bonded Polymers with Bent-Shaped Side Chains and Poly(4-vinylpridine) Backbone: Phase Behavior and Thin Film Morphologies
文献类型：期刊论文
| 作者 | Liu, XS ; Chen, XF ; Wang, JK ; Chen, G ; Zhang, HL |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2014 |
| 卷号 | 47期号:12页码:3917—3925 |
| 关键词 | BLOCK-COPOLYMER SURFACTANT SYSTEMS SUPRAMOLECULAR ASSEMBLIES MESOMORPHIC STRUCTURES LENGTH SCALES ACID POLY(4-VINYLPYRIDINE) MOLECULES NANOSTRUCTURES COMPLEX |
| ISSN号 | 0024-9297 |
| 通讯作者 | xfchen75@suda.edu.cn ; chengang@sinap.ac.cn ; hailiangzhang@xtu.edu.cn |
| 英文摘要 | We investigate the self-assembly behavior of a series of supramolecular hydrogen bonded polymer complexes P4VP(nCBP)(x) in which bent-shaped molecules (nCBP, n = 10,12,14) are attached to a poly(4-vinylpridine) (P4VP) backbone via hydrogen bond interaction in both bulk and thin films. The formation of lamellar and hexagonal columnar (Phi(H)) phases are dependent on the blending ratio of nCBP per vinylpridine unit (x), aliphatic tail length (n), and temperature. When increasing the grafting density x, the phase structure of polymer complexes transform from lamellar to Phi(H) phase. A nonreversible lamellar to Phi(H) phase transition appears in the heating process for P4VP(10CBP)(x) with x >= 0.4, P4VP(12CBP)(x) with x >= 0.3, and P4VP(14CBP)(x) with x >= 0.2. The lamellar and Phi(H) phase are oriented parallel to the substrate in the thin film as verified by both GISAXS and AFM. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000338089400019 |
| 公开日期 | 2015-03-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/14180]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Liu, XS,Chen, XF,Wang, JK,et al. Hydrogen-Bonded Polymers with Bent-Shaped Side Chains and Poly(4-vinylpridine) Backbone: Phase Behavior and Thin Film Morphologies[J]. MACROMOLECULES,2014,47(12):3917—3925. |
| APA | Liu, XS,Chen, XF,Wang, JK,Chen, G,&Zhang, HL.(2014).Hydrogen-Bonded Polymers with Bent-Shaped Side Chains and Poly(4-vinylpridine) Backbone: Phase Behavior and Thin Film Morphologies.MACROMOLECULES,47(12),3917—3925. |
| MLA | Liu, XS,et al."Hydrogen-Bonded Polymers with Bent-Shaped Side Chains and Poly(4-vinylpridine) Backbone: Phase Behavior and Thin Film Morphologies".MACROMOLECULES 47.12(2014):3917—3925. |
入库方式： OAI收割
来源：上海应用物理研究所
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