中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions

文献类型:期刊论文

作者Jiang, BJ ; Song, SZ ; Wang, JQ ; Xie, Y ; Chu, WY ; Li, HF ; Xu, H ; Tian, CG ; Fu, HG
刊名NANO RESEARCH
出版日期2014
卷号7期号:9页码:1280—1290
关键词ENHANCED PHOTOCATALYTIC ACTIVITY RAY-ABSORPTION SPECTROSCOPY PALLADIUM NANOPARTICLES GRAPHITE OXIDE CATALYST FABRICATION REDUCTION RESONANCE FACETS GROWTH
ISSN号1998-0124
通讯作者fuhg@vip.sina.com
英文摘要The introduction of nitrogen significantly decreases the metal particle size and improves the performance of metal-based graphene-supported catalysts. In this work, the density functional theory is used to understand the interaction between nitrogen-doped graphene and Pd@PdO clusters. Experiments show that small size Pd@PdO clusters (1-2 nm) can be grown uniformly on nitrogen-doped graphene sheets by a facile oxidation-reduction method. The nanoscale interaction relationship between nitrogen-doped graphene and Pd@PdO clusters is investigated through X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectra (XAS). The composite catalysts are applied in Suzuki-Miyaura reactions giving high yields and good structural stability. These results have potential impact in design and optimization of future high performance catalyst materials for cross coupling reactions.
收录类别SCI
语种英语
WOS记录号WOS:000342080100005
公开日期2015-03-13
源URL[http://ir.sinap.ac.cn/handle/331007/14274]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式
GB/T 7714
Jiang, BJ,Song, SZ,Wang, JQ,et al. Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions[J]. NANO RESEARCH,2014,7(9):1280—1290.
APA Jiang, BJ.,Song, SZ.,Wang, JQ.,Xie, Y.,Chu, WY.,...&Fu, HG.(2014).Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions.NANO RESEARCH,7(9),1280—1290.
MLA Jiang, BJ,et al."Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions".NANO RESEARCH 7.9(2014):1280—1290.

入库方式: OAI收割

来源:上海应用物理研究所

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