Pt2Cl82- Dimer Formation of [Bmim](2)PtCl4 Ionic Liquid When Confined in Silica Nanopores
文献类型：期刊论文
| 作者 | Li, C ; Wang, YX ; Guo, XJ ; Jiang, Z ; Jiang, FL ; Zhang, WL ; Zhang, WF ; Fu, HY ; Xu, HJ ; Wu, GZ |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2014 |
| 卷号 | 118期号:6页码:3140—3144 |
| 关键词 | CARBON NANOTUBES MELTING-POINT STRUCTURAL-CHARACTERIZATION TRANSITION SIMULATION CRYSTAL |
| ISSN号 | 1932-7447 |
| 通讯作者 | wuguozhong@sinap.ac.cn |
| 英文摘要 | [Bmim](2)PtCl4 (Bmim: 1-butyl-3-methylimidazolium) ionic liquid was confined in porous SiO2 nanoparticles ([Bmim](2)PtCl4@SiO2) with an average pore size of 7.1 nm. The structure of [Bmim](2)PtCl4@SiO2 was investigated through X-ray diffraction and X-ray absorption fine structure (XAFS). The average coordination numbers of Pt species in [Bmim](2)PtCl4 and [Bmim](2)PtCl4@SiO2 were 4.0 and 5.0, respectively. Parts of Pt2+ in [Bmim](2)PtCl4@SiO2 were oxidized to form high-valence Pt4+. The possible forms and structures of Pt in the ionic liquid were analyzed according to the coordination number. XAFS analysis and density functional theory calculations imply the favorable formation of dimer (i.e., Pt2Cl82-) in [Bmim](2)PtCl4@SiO2, in which two bridge Cl atoms were connected to two Pt atoms. In addition, Pt2Cl82- contained mixed-valence platinum (Pt2+ and Pt4+). The results of differential scanning calorimetry also showed that the melting point of this nanoconfined ionic liquid increased. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331493400028 |
| 公开日期 | 2015-03-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/14346]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Li, C,Wang, YX,Guo, XJ,et al. Pt2Cl82- Dimer Formation of [Bmim](2)PtCl4 Ionic Liquid When Confined in Silica Nanopores[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2014,118(6):3140—3144. |
| APA | Li, C.,Wang, YX.,Guo, XJ.,Jiang, Z.,Jiang, FL.,...&Wu, GZ.(2014).Pt2Cl82- Dimer Formation of [Bmim](2)PtCl4 Ionic Liquid When Confined in Silica Nanopores.JOURNAL OF PHYSICAL CHEMISTRY C,118(6),3140—3144. |
| MLA | Li, C,et al."Pt2Cl82- Dimer Formation of [Bmim](2)PtCl4 Ionic Liquid When Confined in Silica Nanopores".JOURNAL OF PHYSICAL CHEMISTRY C 118.6(2014):3140—3144. |
入库方式： OAI收割
来源：上海应用物理研究所
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