Transition-Metal-Catalyzed Oxidation of Metallic Sn in NiO/SnO2 Nanocomposite
文献类型：期刊论文
| 作者 | Hua, CX ; Fang, XP ; Wang, ZX ; Chen, LQ |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014 |
| 卷号 | 20期号:18页码:5487 |
| 关键词 | electrochemistry lithium-ion batteries nanocomposites nickel tin |
| ISSN号 | 0947-6539 |
| 通讯作者 | Wang, ZX (reprint author), Chinese Acad Sci, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing Natl Lab Condensed Matter Phys,Inst Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | It is well accepted that metallic tin as a discharge (reduction) product of SnOx cannot be electrochemically oxidized below 3.00V versus Li+/Li-0 due to the high stability of Li2O, though a similar oxidation can usually occur for a transition metal formed from the corresponding oxide. In this work, nanosized Ni2SnO4 and NiO/SnO2 nanocomposite were synthesized by coprecipitation reactions and subsequent heat treatment. Owing to the catalytic effect of nanosized metallic nickel, metallic tin can be electrochemically oxidized to SnO2 below 3.00V. As a result, the reversible lithium-storage capacities of the nanocomposite reach 970mAhg(-1) or above, much higher than the theoretical capacity (ca. 750mAhg(-1)) of SnO2, NiO, or their composites. These findings extend the well-known electrochemical conversion reaction to non-transition-metal compounds and may have important applications, for example, in constructing high-capacity electrode materials and efficient catalysts. |
| 资助信息 | National Natural Science Foundation of China [51372268]; National 973 Program of China [2009CB 220100] |
| 语种 | 英语 |
| 公开日期 | 2015-04-14 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/58960]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hua, CX,Fang, XP,Wang, ZX,et al. Transition-Metal-Catalyzed Oxidation of Metallic Sn in NiO/SnO2 Nanocomposite[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(18):5487. |
| APA | Hua, CX,Fang, XP,Wang, ZX,&Chen, LQ.(2014).Transition-Metal-Catalyzed Oxidation of Metallic Sn in NiO/SnO2 Nanocomposite.CHEMISTRY-A EUROPEAN JOURNAL,20(18),5487. |
| MLA | Hua, CX,et al."Transition-Metal-Catalyzed Oxidation of Metallic Sn in NiO/SnO2 Nanocomposite".CHEMISTRY-A EUROPEAN JOURNAL 20.18(2014):5487. |
入库方式： OAI收割
来源：物理研究所
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