Seed-Mediated Synthesis of Gold Tetrahedra in High Purity and with Tunable, Well-Controlled Sizes
文献类型:期刊论文
作者 | Zheng, YQ ; Liu, WY ; Lv, T ; Luo, M ; Hu, HF ; Lu, P ; Choi, SI ; Zhang, C ; Tao, J ; Zhu, YM ; Li, ZY ; Xia, YN |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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出版日期 | 2014 |
卷号 | 9期号:9页码:2635 |
关键词 | gold nanocrystals seeded growth shape control tetrahedron |
ISSN号 | 1861-4728 |
通讯作者 | Xia, YN (reprint author), Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA. |
中文摘要 | We report a facile synthesis of Au tetrahedra in high purity and with tunable, well-controlled sizes via seed-mediated growth. The success of this synthesis relies on the use of single-crystal, spherical Au nanocrystals as the seeds and manipulation of the reaction kinetics to induce an unsymmetrical growth pattern for the seeds. In particular, the dropwise addition of a precursor solution with a syringe pump, assisted by cetyltrimethylammonium chloride and bromide at appropriate concentrations, was found to be critical to the formation of Au tetrahedra in high purity. Their sizes could be readily tuned in the range of 30-60 nm by simply varying the amount of precursor added to the reaction solution. The current strategy not only enables the synthesis of Au tetrahedra with tunable and controlled sizes but also provides a facile and versatile approach to reducing the symmetry of nanocrystals made of a face-centered cubic lattice. |
资助信息 | NSF [DMR-1215034]; startup funds from Georgia Institute of Technology; NSF |
语种 | 英语 |
公开日期 | 2015-04-14 |
源URL | [http://ir.iphy.ac.cn/handle/311004/58961] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Zheng, YQ,Liu, WY,Lv, T,et al. Seed-Mediated Synthesis of Gold Tetrahedra in High Purity and with Tunable, Well-Controlled Sizes[J]. CHEMISTRY-AN ASIAN JOURNAL,2014,9(9):2635. |
APA | Zheng, YQ.,Liu, WY.,Lv, T.,Luo, M.,Hu, HF.,...&Xia, YN.(2014).Seed-Mediated Synthesis of Gold Tetrahedra in High Purity and with Tunable, Well-Controlled Sizes.CHEMISTRY-AN ASIAN JOURNAL,9(9),2635. |
MLA | Zheng, YQ,et al."Seed-Mediated Synthesis of Gold Tetrahedra in High Purity and with Tunable, Well-Controlled Sizes".CHEMISTRY-AN ASIAN JOURNAL 9.9(2014):2635. |
入库方式: OAI收割
来源:物理研究所
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