Controllable synthesis of zirconia nano-powders using vapor-phase hydrolysis and theoretical analysis
文献类型：期刊论文
| 作者 | Wang, Q ; Li, CH ; Guo, M ; Hu, CW ; Xie, YC |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2014 |
| 卷号 | 2期号:5页码:1346 |
| ISSN号 | 2050-7488 |
| 通讯作者 | Wang, Q (reprint author), Capital Normal Univ, Lab Microsized Funct Mat, Beijing 100048, Peoples R China. |
| 中文摘要 | The feasibility of controllable synthesis of nano-crystalline ZrO2 powders using vapor-phase hydrolysis was studied. XRD, SEM, TEM, BET and TG-DTA methods were used to investigate the phase composition, particle size, and agglomeration. The formation process of the nano-particles was also analyzed with the classic Smoluchowski theory, the coupled cluster theory [CCSD(T)]/aT and/or Moller-Plesset perturbation theory (MP2)/aT. The results show that the morphology and size of the ZrO2 nano-particles were very much dependent on the ratio of ZrCl4 : H2O, which played an important part in determining the characteristics of the ZrO2 nano-particles. By increasing the concentration of water to decrease their collision rate and prevent nano-particle agglomeration, the size distribution of the nano-particle product would be decreased and a more monodisperse nano-particle product would be collected. In particular, the best characteristics were obtained using a precursor ratio of 1 : 40 (ZrCl4 : H2O). The nano-powders had a small particle size (15 nm), a high degree of crystallinity and very weak agglomeration, in a continuous instead of batch operation. This route is free of powder drying and calcination processes that are essential for wet chemical preparation, contributing to less agglomeration. |
| 资助信息 | Natural Science Foundation of China (NSFC) [20801036, 51002180, 20731002, 20871016, 10876002, 91022006, 20973023]; 111 Project [B07012]; Program for New Century Excellent Talents in University; Beijing Institute of Technology [ZDKT08-01, YBKT09-13]; Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) [200800070015]; Funding Project for Science and Technology Program of Beijing Municipal Commission [Z09010300820902]; Key Foundation of China Academy of Engineering Physics [2009A0302017]; Open Fund of State Key Laboratory of Explosion Science and Technology |
| 语种 | 英语 |
| 公开日期 | 2015-04-14 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/59218]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, Q,Li, CH,Guo, M,et al. Controllable synthesis of zirconia nano-powders using vapor-phase hydrolysis and theoretical analysis[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(5):1346. |
| APA | Wang, Q,Li, CH,Guo, M,Hu, CW,&Xie, YC.(2014).Controllable synthesis of zirconia nano-powders using vapor-phase hydrolysis and theoretical analysis.JOURNAL OF MATERIALS CHEMISTRY A,2(5),1346. |
| MLA | Wang, Q,et al."Controllable synthesis of zirconia nano-powders using vapor-phase hydrolysis and theoretical analysis".JOURNAL OF MATERIALS CHEMISTRY A 2.5(2014):1346. |
入库方式： OAI收割
来源：物理研究所
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