A general and rapid synthesis of metal sulphides hollow spheres that have properties enhanced by salt-assisted aerosol decomposition: a case of ZnS and other multicomponent solid solutions
文献类型：期刊论文
| 作者 | Zou, W ; Chen, J ; Hu, L ; Li, Q ; Yao, X ; Gu, L ; Deng, JX ; Yu, RB ; Xing, XR |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2014 |
| 卷号 | 2期号:40页码:8564 |
| ISSN号 | 2050-7526 |
| 通讯作者 | Chen, J (reprint author), Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China. |
| 中文摘要 | Synthesis of hollow structures of metal sulphides generally involves various templates and complex chemical processing. In the present study, a general and rapid method of salt-assisted aerosol decomposition (SAD) is presented for the synthesis of hollow spheres of various metal sulfides, including ZnS, ternary sulfides, and solid solutions. The NaCl salt plays a critical role in the formation of hollow spheres of metal sulfides. The hollow spherical microstructure was formed from solid by using a small amount of water soluble NaCl salt. The formation of metal sulphide hollow spheres differs from previous mechanisms and is referred to as molten salt heterogeneous nucleation (MSHN). The present method offers the most promising advantage for controlling the multicomponent composition of hollow spheres. Furthermore, hollow spheres of sulphides have much enhanced properties such as photoluminescence of ZnS:Mn2+ and photocatalytic dye degradation of ZnIn2S4 due to the role of molten salt in the promotion of crystallization, The present method could be explored further by applying the process to other compounds such as sulfides, oxides, and nitrides. |
| 资助信息 | National Natural Science Foundation of China [21322102, 21031005, 21231001]; Program for Changjiang Scholars and Innovative Research Team in University [IRT1207]; Foundation for the Author of National Excellent Doctoral Dissertation of P.R. China [201039]; Fok Ying Tung Education Foundation [131047]; Program for New Century Excellent Talents in University [NCET-11-0573] |
| 语种 | 英语 |
| 公开日期 | 2015-04-14 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/59220]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zou, W,Chen, J,Hu, L,et al. A general and rapid synthesis of metal sulphides hollow spheres that have properties enhanced by salt-assisted aerosol decomposition: a case of ZnS and other multicomponent solid solutions[J]. JOURNAL OF MATERIALS CHEMISTRY C,2014,2(40):8564. |
| APA | Zou, W.,Chen, J.,Hu, L.,Li, Q.,Yao, X.,...&Xing, XR.(2014).A general and rapid synthesis of metal sulphides hollow spheres that have properties enhanced by salt-assisted aerosol decomposition: a case of ZnS and other multicomponent solid solutions.JOURNAL OF MATERIALS CHEMISTRY C,2(40),8564. |
| MLA | Zou, W,et al."A general and rapid synthesis of metal sulphides hollow spheres that have properties enhanced by salt-assisted aerosol decomposition: a case of ZnS and other multicomponent solid solutions".JOURNAL OF MATERIALS CHEMISTRY C 2.40(2014):8564. |
入库方式： OAI收割
来源：物理研究所
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