a A Resistance-Switchable and Ferroelectric Metal Organic Framework
文献类型:期刊论文
作者 | Pan, L ; Liu, G ; Li, H ; Meng, S ; Han, L ; Shang, J ; Chen, B ; Platero-Prats, AE ; Lu, W ; Zou, XD ; Li, RW |
刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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出版日期 | 2014 |
卷号 | 136期号:50页码:17477 |
ISSN号 | 0002-7863 |
通讯作者 | Han, L (reprint author), Ningbo Univ, State Key Lab Base Novel Funct Mat & Preparat Sci, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China. |
中文摘要 | The ever-emerging demands on miniaturization of electronic devices have pushed the development of innovative materials with desired properties. One major endeavor is the development of organic- or organic-inorganic hybrid-based electronics as alternatives or supplements to silicon-based devices. Herein we report the first observation of the coexistence of resistance switching and ferroelectricity in a metal-organic framework (MOF) material, [InC16H11N2O8]center dot 1.5H(2)O, denoted as RSMOF-1. The electrical resistance of RSMOF-1 can be turned on and off repeatedly with a current ratio of 30. A first-principles molecular dynamics simulation suggests that the resistive switching effect is related to the ferroelectric transition of N center dot center dot center dot H-O center dot center dot center dot H-N bridge-structured dipoles of the guest water molecules and the amino-tethered MOF nanochannel. The discovery of the resistive switching effect and ferroelectricity in MOFs offers great potential for the physical implementation of novel electronics for next-generation digital processing and communication. |
资助信息 | State Key Project of Fundamental Research of China (973 Program) [2012CB933004, 2009CB930803]; Chinese Academy of Sciences; National Natural Science Foundation of China [11274321, 11474295, 21071087, 91122012, 51303194, 61328402]; Ningbo Science and Technology Innovation Team [2009B21005, 2011B82004]; Ningbo Natural Science Foundation [2013A610031]; Swedish Research Council (VR); Swedish Governmental Agency for Innovation Systems (VINNOVA) |
语种 | 英语 |
公开日期 | 2015-04-14 |
源URL | [http://ir.iphy.ac.cn/handle/311004/59289] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Pan, L,Liu, G,Li, H,et al. a A Resistance-Switchable and Ferroelectric Metal Organic Framework[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(50):17477. |
APA | Pan, L.,Liu, G.,Li, H.,Meng, S.,Han, L.,...&Li, RW.(2014).a A Resistance-Switchable and Ferroelectric Metal Organic Framework.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(50),17477. |
MLA | Pan, L,et al."a A Resistance-Switchable and Ferroelectric Metal Organic Framework".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.50(2014):17477. |
入库方式: OAI收割
来源:物理研究所
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