Identifying Li+ ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range
文献类型：期刊论文
| 作者 | Wang, SF ; Ben, LB ; Li, H ; Chen, LQ |
| 刊名 | SOLID STATE IONICS
 |
| 出版日期 | 2014 |
| 卷号 | 268页码:110 |
| 关键词 | Lithium titanium phosphate Al-doping Low temperature Bulk conductivity Grain boundary conductivity Impedance analysis |
| ISSN号 | 0167-2738 |
| 通讯作者 | Li, H (reprint author), Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | A series of Li1+xAlxTi2-x(PO4)(3) samples (x = 0-0.4) were prepared by solid state reaction and were characterized. Lattice parameters a and c decrease continuously with increase of Al content. The relative density of the Al-doped samples is about 97%, which is much higher than 75% of the undoped LiTi2(PO4)(3) sample. Detailed ac impedance measurements from - 150 degrees C to 60 degrees C reveal clearly that three electrical response regions with different relaxation time constants coexist in the undoped LiTi2(PO4)(3) sample but only two in all Al-doped samples. The bulk ionic conductivities for the Al-doped samples show no significant variation from x = 0.1 to x = 0.4. Their ionic conductivities are slightly higher than those of the undoped sample. However, this increase is not caused by increasing bulk ionic conductivity through introducing more lithium ions via doping, but it is mainly attributed to a densification effect. (C) 2014 Elsevier B.V. All rights reserved. |
| 资助信息 | Beijing ST Project [Z13111000340000]; NSFC [51325206]; Chinese Academy of Sciences [XDA09010202] |
| 语种 | 英语 |
| 公开日期 | 2015-04-14 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/59753]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, SF,Ben, LB,Li, H,et al. Identifying Li+ ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range[J]. SOLID STATE IONICS,2014,268:110. |
| APA | Wang, SF,Ben, LB,Li, H,&Chen, LQ.(2014).Identifying Li+ ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range.SOLID STATE IONICS,268,110. |
| MLA | Wang, SF,et al."Identifying Li+ ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range".SOLID STATE IONICS 268(2014):110. |
入库方式： OAI收割
来源：物理研究所
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