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Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials
文献类型:期刊论文
作者 | Zhang, H (Zhang, Hui); Zhang, M (Zhang, Min)![]() ![]() ![]() ![]() ![]() |
刊名 | CRYSTAL GROWTH & DESIGN
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出版日期 | 2015 |
卷号 | 15期号:1页码:523-529 |
关键词 | NONLINEAR-OPTICAL PROPERTIES HIGH-PRESSURE SYNTHESIS BAB2O4-NAF SYSTEM PHASE-EQUILIBRIA CRYSTAL-STRUCTURES GROWTH UV BORATE OXIDE COEFFICIENTS |
ISSN号 | 1528-7483 |
通讯作者 | Zhang, M |
英文摘要 | Birefringent materials are of great importance in optical communication and the laser industry, as they can modulate the polarization of light. Limited by their transparency range, few birefringent materials, except alpha-BaB2O4 (alpha-BBO), can be practically used in the deep ultraviolet (UV) region. However, alpha-BBO suffers from a phase transition and does not have enough transparency in the deep UV region. By introducing the relatively small alkali metal Na+ cation and the F anion to keep the favorable structural features of alpha-BBO, we report a new birefringent crystal Na3Ba2(B3O6)(2)F (NBBF), which has the desirable optical properties. NBBF not only maintains the large birefringence (Delta n = n(o) - n(e) = 0.2554-0.0750 from 175 nm to 3.35 mu m) and extends its UV cutoff edge to 175 nm (14 nm shorter than alpha-BBO) but also eliminates the phase transition and has the lowest growth temperature (820 degrees C) among birefringent materials. These results demonstrate that NBBF is an attractive candidate for the next generation of deep UV birefringent materials. |
收录类别 | SCI |
WOS记录号 | WOS:000347667500065 |
公开日期 | 2015-03-11 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/4213] ![]() |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_资源化学研究室 新疆理化技术研究所_材料物理与化学研究室 |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA |
推荐引用方式 GB/T 7714 | Zhang, H ,Zhang, M ,Pan, SL ,et al. Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials[J]. CRYSTAL GROWTH & DESIGN,2015,15(1):523-529. |
APA | Zhang, H .,Zhang, M .,Pan, SL .,Yang, ZH .,Wang, Z .,...&Poeppelmeier, KR .(2015).Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials.CRYSTAL GROWTH & DESIGN,15(1),523-529. |
MLA | Zhang, H ,et al."Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials".CRYSTAL GROWTH & DESIGN 15.1(2015):523-529. |
入库方式: OAI收割
来源:新疆理化技术研究所
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