Synergistic Effects in Porous Mn-Co Mixed Oxide Nanorods Enhance Catalytic Deep Oxidation of Benzene
文献类型：期刊论文
| 作者 | Tang, Wenxiang1,2; Li, Wenhui1,2; Li, Dongyan1; Liu, Gang1,2; Wu, Xiaofeng1; Chen, Yunfa1
|
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 144期号:11页码:1900-1910 |
| 关键词 | Environmental catalysis Total oxidation Nanorods Mn-Co mixed oxide Interaction Benzene |
| ISSN号 | 1011-372X |
| 其他题名 | Catal. Lett. |
| 中文摘要 | A series of Mn-Co mixed oxide nanorods with homogeneous worm-like pores were facilely prepared by a sol-gel chelating method. With incorporating Mnn+ into Co3O4, the formation of solid solution with spinel structure inhibits the growth of nanoparticles which is benefit to keep smaller crystal size and higher surface area. XPS and H-2-TPR results indicate that there are more high manganese valence (Mn3+ and Mn4+) and adsorbed oxygen species as well as low-temperature reducibility for the mixed oxide catalysts, as a result of the strong synergistic effect between Mn and Co species in solid solution, which will play a key role in catalytic activity. The as-prepared catalysts were used for catalytic deep oxidation of benzene which is a typical carcinogenic VOC. The catalytic activities over the mixed oxides with varied mole ratio are much higher than that on the single MnOx or Co3O4. The Mn5Co5 sample showed the best activity with T-90% for benzene conversions into CO2 were low to 237 A degrees C at a high space velocity of 120,000 mL g(-1) h(-1). |
| 英文摘要 | A series of Mn-Co mixed oxide nanorods with homogeneous worm-like pores were facilely prepared by a sol-gel chelating method. With incorporating Mnn+ into Co3O4, the formation of solid solution with spinel structure inhibits the growth of nanoparticles which is benefit to keep smaller crystal size and higher surface area. XPS and H-2-TPR results indicate that there are more high manganese valence (Mn3+ and Mn4+) and adsorbed oxygen species as well as low-temperature reducibility for the mixed oxide catalysts, as a result of the strong synergistic effect between Mn and Co species in solid solution, which will play a key role in catalytic activity. The as-prepared catalysts were used for catalytic deep oxidation of benzene which is a typical carcinogenic VOC. The catalytic activities over the mixed oxides with varied mole ratio are much higher than that on the single MnOx or Co3O4. The Mn5Co5 sample showed the best activity with T-90% for benzene conversions into CO2 were low to 237 A degrees C at a high space velocity of 120,000 mL g(-1) h(-1). |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | VOLATILE ORGANIC-COMPOUNDS ; INDOOR AIR-QUALITY ; CALCINATION TEMPERATURE ; METHANE COMBUSTION ; MANGANESE ; TOLUENE ; COPPER ; OXYGEN ; CO3O4 ; VOCS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000343136100015 |
| 公开日期 | 2014-12-01 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11687]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Wenxiang,Li, Wenhui,Li, Dongyan,et al. Synergistic Effects in Porous Mn-Co Mixed Oxide Nanorods Enhance Catalytic Deep Oxidation of Benzene[J]. CATALYSIS LETTERS,2014,144(11):1900-1910. |
| APA | Tang, Wenxiang,Li, Wenhui,Li, Dongyan,Liu, Gang,Wu, Xiaofeng,&Chen, Yunfa.(2014).Synergistic Effects in Porous Mn-Co Mixed Oxide Nanorods Enhance Catalytic Deep Oxidation of Benzene.CATALYSIS LETTERS,144(11),1900-1910. |
| MLA | Tang, Wenxiang,et al."Synergistic Effects in Porous Mn-Co Mixed Oxide Nanorods Enhance Catalytic Deep Oxidation of Benzene".CATALYSIS LETTERS 144.11(2014):1900-1910. |
入库方式： OAI收割
来源：过程工程研究所
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