Mesoporous Cu-Mn oxides with high surface area (similar to 221 m(2) g(-1)) were successfully obtained through a simple co-nanocasting approach using siliceous SBA-15 mesoporous material as a hard template. Their catalytic performances for deep oxidation of benzene were tested and physicochemical properties were characterized in detail by means of N-2-physisorption, XRD, XPS, H-2-TPR, SEM-EDX and TEM. The asprepared mesoporous Cu-Mn oxides display superior catalytic activity and the temperature required for achieving a benzene conversion of 90% has been obtained at about 234 degrees C over sample Cu0.6Mn, which is 131 degrees C lower than that on the Cu-Mn oxide prepared by co-precipitation method using NaOH. The apparent activation energy over nanocasted catalyst was low to 45.0 kJ mol(-1.) Nanocasting process provides a limited nanoreactor for the formation of Cu-Mn composite oxide which makes the Cu-Mn oxides owing small particle size, high surface area, rich surface adsorbed oxygen species, low temperature reducibility and promoting interaction of Cu-Mn species. These characters generated by nanocasting method are responsible for its better catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.