Structure, Interaction and Hydrogen Bond
文献类型：期刊论文
| 作者 | Dong, Kun2; Wang, Qian2; Lu, Xingmei2; Zhou, Qing2; Zhang, Suojiang2; Zhang, S; Wang, J; Lu, X; Zhou, Q |
| 刊名 | STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS
 |
| 出版日期 | 2014 |
| 卷号 | 151期号:B页码:1-38 |
| 关键词 | Ionic liquid Structure Interaction Property Application |
| ISSN号 | 0081-5993 |
| 其他题名 | Struct. Bond. |
| 中文摘要 | Ionic liquids (ILs), as green solvents, have attracted amazing interest and their potential applications have prompted a large amount of research and investment, and some of the results have been inspiring. In recent years, in combination with cations and anions, some new ILs have been synthesized in the laboratory. However, compared with simple solid salts, the structures of ILs are complicated and their properties vary considerably. It is thus very time consuming to explore ILs experimentally when facing the huge number of ionic combinations. A molecular-based understanding can reveal the quantitative correlation between structures and properties, and is thus an important subject in the study of ILs. The unusual complexity of ionic interactions renders molecular-based interpretations difficult and gives rise to controversies about the structure of the ILs. Herein we discuss the ion-pair, cluster and X-ray crystals structures and their relationship with the properties of many typical ILs, especially imidazolium-based. In the ILs, apart from the strong electrostatic forces, non-covalent H-bonds and van der Waals (dispersion, induce forces) are examined and are shown to have a decisive effect on the properties of ILs. |
| 英文摘要 | Ionic liquids (ILs), as green solvents, have attracted amazing interest and their potential applications have prompted a large amount of research and investment, and some of the results have been inspiring. In recent years, in combination with cations and anions, some new ILs have been synthesized in the laboratory. However, compared with simple solid salts, the structures of ILs are complicated and their properties vary considerably. It is thus very time consuming to explore ILs experimentally when facing the huge number of ionic combinations. A molecular-based understanding can reveal the quantitative correlation between structures and properties, and is thus an important subject in the study of ILs. The unusual complexity of ionic interactions renders molecular-based interpretations difficult and gives rise to controversies about the structure of the ILs. Herein we discuss the ion-pair, cluster and X-ray crystals structures and their relationship with the properties of many typical ILs, especially imidazolium-based. In the ILs, apart from the strong electrostatic forces, non-covalent H-bonds and van der Waals (dispersion, induce forces) are examined and are shown to have a decisive effect on the properties of ILs. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TEMPERATURE IONIC LIQUIDS ; MOLECULAR-DYNAMICS SIMULATION ; DIELS-ALDER REACTIONS ; X-RAY-DIFFRACTION ; MOLTEN-SALTS ; CRYSTAL-STRUCTURES ; 1-N-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; PHYSICOCHEMICAL PROPERTIES ; PHYSICAL-PROPERTIES ; INITIO CALCULATIONS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000344737400002 |
| 出版者 | Springer-Verlag Berlin |
| 公开日期 | 2015-04-01 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11725]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Ion Liquids Clean Proc,Key Lab Green Proc, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Kun,Wang, Qian,Lu, Xingmei,et al. Structure, Interaction and Hydrogen Bond[J]. STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS,2014,151(B):1-38. |
| APA | Dong, Kun.,Wang, Qian.,Lu, Xingmei.,Zhou, Qing.,Zhang, Suojiang.,...&Zhou, Q.(2014).Structure, Interaction and Hydrogen Bond.STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS,151(B),1-38. |
| MLA | Dong, Kun,et al."Structure, Interaction and Hydrogen Bond".STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS 151.B(2014):1-38. |
入库方式： OAI收割
来源：过程工程研究所
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