Waste carbide slag as a solid base catalyst for effective synthesis of biodiesel via transesterification of soybean oil with methanol
文献类型：期刊论文
| 作者 | Li, Feng-Jiao1,2 ; Li, Hui-Quan1; Wang, Li-Guo1; Cao, Yan1
|
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 131期号:MAR页码:421-429 |
| 关键词 | Biodiesel Carbide slag Soybean oil Transesterification Solid base |
| ISSN号 | 0378-3820 |
| 其他题名 | Fuel Process. Technol. |
| 中文摘要 | A highly efficient solid base catalyst was prepared from waste carbide slag and tested for biodiesel production from soybean oil with methanol. The effect of calcination temperature for carbide slag and various reaction parameters on the catalytic performances was systematically investigated. The carbide slag waste calcined at 650 degrees C (CS-650) exhibited 91.3% yield of fatty acid methyl esters (FAME) at reaction temperature of 65 degrees C, methanol/oil molar ratio of 9, catalyst/oil mass ratio of 1.0 wt.% within a short reaction time of 30 min, which was much higher than that of commercial CaO. Furthermore, the relationship between the surface basicity and activity indicated that stronger basicity was responsible for the higher catalytic activity. The merits of high catalytic activity, low cost, and abundant storage make the waste carbide slag a promising catalyst in the production of biodiesel. (C) 2014 Published by Elsevier B.V. |
| 英文摘要 | A highly efficient solid base catalyst was prepared from waste carbide slag and tested for biodiesel production from soybean oil with methanol. The effect of calcination temperature for carbide slag and various reaction parameters on the catalytic performances was systematically investigated. The carbide slag waste calcined at 650 degrees C (CS-650) exhibited 91.3% yield of fatty acid methyl esters (FAME) at reaction temperature of 65 degrees C, methanol/oil molar ratio of 9, catalyst/oil mass ratio of 1.0 wt.% within a short reaction time of 30 min, which was much higher than that of commercial CaO. Furthermore, the relationship between the surface basicity and activity indicated that stronger basicity was responsible for the higher catalytic activity. The merits of high catalytic activity, low cost, and abundant storage make the waste carbide slag a promising catalyst in the production of biodiesel. (C) 2014 Published by Elsevier B.V. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
| 关键词[WOS] | HETEROGENEOUS CATALYSTS ; OYSTER SHELL ; ACTIVE PHASE ; MUSSEL SHELL ; PALM OIL ; CAO ; ZEOLITE ; OPTIMIZATION ; SURFACE ; OXIDES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000348881700052 |
| 公开日期 | 2015-04-01 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11766]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Feng-Jiao,Li, Hui-Quan,Wang, Li-Guo,et al. Waste carbide slag as a solid base catalyst for effective synthesis of biodiesel via transesterification of soybean oil with methanol[J]. FUEL PROCESSING TECHNOLOGY,2015,131(MAR):421-429. |
| APA | Li, Feng-Jiao,Li, Hui-Quan,Wang, Li-Guo,&Cao, Yan.(2015).Waste carbide slag as a solid base catalyst for effective synthesis of biodiesel via transesterification of soybean oil with methanol.FUEL PROCESSING TECHNOLOGY,131(MAR),421-429. |
| MLA | Li, Feng-Jiao,et al."Waste carbide slag as a solid base catalyst for effective synthesis of biodiesel via transesterification of soybean oil with methanol".FUEL PROCESSING TECHNOLOGY 131.MAR(2015):421-429. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。