Mesoporous composite of LiFePO4 and carbon microspheres as positive-electrode materials for lithium-ion batteries
文献类型：期刊论文
| 作者 | Tan, Qiangqiang1; Lv, Cheng1,2; Xu, Yuxing1; Yang, Jun1 |
| 刊名 | PARTICUOLOGY
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 17期号:dec页码:106-113 |
| 关键词 | LiFePO4 Composite Nanoparticle Hydrothermal approach Positive-electrode material Lithium-ion battery |
| ISSN号 | 1674-2001 |
| 其他题名 | Particuology |
| 中文摘要 | Mesoporous LiFePO4/C microspheres consisting of LiFePO4 nanoparticles are successfully fabricated by an eco-friendly hydrothermal approach combined with high-temperature calcinations using cost-effective LiOH and Fe3+ salts as raw materials. In this strategy, pure mesoporous LiFePO4 microspheres, which are composed of LiFePO4 nanoparticles, were uniformly coated with carbon (similar to 1.5 nm). Benefiting from this unique architecture, these mesoporous LiFePO4/C microspheres can be closely packed, having high tap density. The initial discharge capacity of LiFePO4/C microspheres as positive-electrode materials for lithium-ion batteries could reach 165.3 mAh/g at 0.1 C rate, which is notably close to the theoretical capacity of LiFePO4 due to the large BET surface area, which provides for a large electrochemically available surface for the active material and electrolyte. The material also exhibits high rate capability (similar to 100 mAh/g at 8 C) and good cycling stability (capacity retention of 92.2% after 400 cycles at 8 C rate). (C) 2014 Published by Elsevier B.V. on behalf of Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. |
| 英文摘要 | Mesoporous LiFePO4/C microspheres consisting of LiFePO4 nanoparticles are successfully fabricated by an eco-friendly hydrothermal approach combined with high-temperature calcinations using cost-effective LiOH and Fe3+ salts as raw materials. In this strategy, pure mesoporous LiFePO4 microspheres, which are composed of LiFePO4 nanoparticles, were uniformly coated with carbon (similar to 1.5 nm). Benefiting from this unique architecture, these mesoporous LiFePO4/C microspheres can be closely packed, having high tap density. The initial discharge capacity of LiFePO4/C microspheres as positive-electrode materials for lithium-ion batteries could reach 165.3 mAh/g at 0.1 C rate, which is notably close to the theoretical capacity of LiFePO4 due to the large BET surface area, which provides for a large electrochemically available surface for the active material and electrolyte. The material also exhibits high rate capability (similar to 100 mAh/g at 8 C) and good cycling stability (capacity retention of 92.2% after 400 cycles at 8 C rate). (C) 2014 Published by Elsevier B.V. on behalf of Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Engineering ; Materials Science |
| 关键词[WOS] | HYDROTHERMAL SYNTHESIS ; IRON PHOSPHATE ; ELECTROCHEMICAL PROPERTIES ; CATHODE MATERIAL ; COATED LIFEPO4 ; PERFORMANCE ; MORPHOLOGY ; CHEMISTRY ; TEMPLATE ; ROUTE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000347656700016 |
| 公开日期 | 2015-04-01 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11828]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Qiangqiang,Lv, Cheng,Xu, Yuxing,et al. Mesoporous composite of LiFePO4 and carbon microspheres as positive-electrode materials for lithium-ion batteries[J]. PARTICUOLOGY,2014,17(dec):106-113. |
| APA | Tan, Qiangqiang,Lv, Cheng,Xu, Yuxing,&Yang, Jun.(2014).Mesoporous composite of LiFePO4 and carbon microspheres as positive-electrode materials for lithium-ion batteries.PARTICUOLOGY,17(dec),106-113. |
| MLA | Tan, Qiangqiang,et al."Mesoporous composite of LiFePO4 and carbon microspheres as positive-electrode materials for lithium-ion batteries".PARTICUOLOGY 17.dec(2014):106-113. |
入库方式： OAI收割
来源：过程工程研究所
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