Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts: The effects of chlorine substituents
文献类型：期刊论文
| 作者 | Wang, J. ; Wang, X. ; Liu, X. L. ; Zhu, T. Y. ; Guo, Y. Y. ; Qi, H. |
| 刊名 | Catalysis Today
 |
| 出版日期 | 2015 |
| 页码 | 92-99 |
| 关键词 | Catalytic oxidation Chlorobenzene 1 V2O5/TiO2 FTIR VANADIA-TITANIA CATALYSTS OXIDE-BASED FORMULATIONS DIBENZO-P-DIOXINS IN-SITU FTIR PT/GAMMA-AL2O3 CATALYST PILOT INCINERATOR NITRIC-OXIDE CHLOROBENZENE COMBUSTION 1 3 2-DICHLOROBENZENE 5-Trichlorobenzene |
| 其他题名 | Catal. Today |
| 中文摘要 | Chlorobenzene and 1,3,5-trichlorobenzene were chosen as model pollutants of chlorinated benzenes. Catalytic (kinetic) studies and in-situ FTIR experiments were conducted over V2O5/TiO2 catalysts to investigate the oxidation behavior of these two chlorinated benzenes. Different oxidation rates were observed in the catalytic study, which was ascribed to their molecular structural properties. Oxidation products and by-products were analyzed both on-line by GC and off-line by GC-MS, and slight difference was observed for these two chlorinated benzenes. Similar surface species on the catalysts could be easily identified in the in-situ FTIR curves. Supported by these results, a possible reaction pathway for catalytic oxidation of 1,3,5-trichlorobenzene was accordingly proposed. Noteworthy, the effect of the chlorinated degree on the catalytic oxidation was discussed, and it is well demonstrated that the structural and electronic factors of the chlorinated benzenes, and the influence of chlorine to the active vanadium sites, play important roles in the oxidation process. (C) 2014 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000345503700014 |
| 公开日期 | 2015-04-01 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11837]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 推荐引用方式 GB/T 7714 | Wang, J.,Wang, X.,Liu, X. L.,et al. Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts: The effects of chlorine substituents[J]. Catalysis Today,2015:92-99. |
| APA | Wang, J.,Wang, X.,Liu, X. L.,Zhu, T. Y.,Guo, Y. Y.,&Qi, H..(2015).Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts: The effects of chlorine substituents.Catalysis Today,92-99. |
| MLA | Wang, J.,et al."Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts: The effects of chlorine substituents".Catalysis Today (2015):92-99. |
入库方式： OAI收割
来源：过程工程研究所
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