中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of metal ions on the hydrolysis of bamboo biomass in 1-butyl-3-methylimidazolium chloride with dilute acid as catalyst

文献类型:期刊论文

作者Wang, Nan1; Zhang, Jie1; Wang, Honghui1; Li, Qiang2; Wei, Sun'an1; Wang, Dan1
刊名BIORESOURCE TECHNOLOGY
出版日期2014-12-01
卷号173期号:0页码:399-405
关键词Bamboo biomass Ionic liquids Metal ions Hydrolysis Dilute hydrochloride acid
ISSN号0960-8524
其他题名Bioresour. Technol.
中文摘要In this study, the effects of six metal ions including Na+, K+, Mg2+, Ca2+, Cu2+ and Fe3+ on hydrolysis of bamboo biomass by diluted hydrochloride acid (HCl) in ionic liquid [C(4)mim] Cl under mild conditions was investigated. These metal ions as co-catalysts exhibited significant effects on accelerating the hydrolysis process and improving the yield of total reducing sugar compared to single diluted hydrochloride acid hydrolysis in [C(4)mim] Cl at the same conditions. The most effective ion was Cu2+ and the total reducing sugar yield of 67.1% was achieved at 100 degrees C with CuCl2 as co-catalyst after 4-h reaction. The total reducing sugar yield was increased by about 7% and the reaction time was decreased by 3 h. The kinetic model was also investigated to give an insight into the mechanism of hydrolysis process. (C) 2014 Elsevier Ltd. All rights reserved.
英文摘要In this study, the effects of six metal ions including Na+, K+, Mg2+, Ca2+, Cu2+ and Fe3+ on hydrolysis of bamboo biomass by diluted hydrochloride acid (HCl) in ionic liquid [C(4)mim] Cl under mild conditions was investigated. These metal ions as co-catalysts exhibited significant effects on accelerating the hydrolysis process and improving the yield of total reducing sugar compared to single diluted hydrochloride acid hydrolysis in [C(4)mim] Cl at the same conditions. The most effective ion was Cu2+ and the total reducing sugar yield of 67.1% was achieved at 100 degrees C with CuCl2 as co-catalyst after 4-h reaction. The total reducing sugar yield was increased by about 7% and the reaction time was decreased by 3 h. The kinetic model was also investigated to give an insight into the mechanism of hydrolysis process. (C) 2014 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Technology
类目[WOS]Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
研究领域[WOS]Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]BIOETHANOL PRODUCTION ; ENZYMATIC-HYDROLYSIS ; SUGARCANE BAGASSE ; REDUCING SUGAR ; CORN STOVER ; PRETREATMENT ; LIQUID ; CELLULOSE ; SALTS ; LIGNOCELLULOSE
收录类别SCI
原文出处://WOS:000344120200050
语种英语
WOS记录号WOS:000344120200050
公开日期2015-04-01
源URL[http://ir.ipe.ac.cn/handle/122111/11843]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chongqing Univ, Dept Chem Engn, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wang, Nan,Zhang, Jie,Wang, Honghui,et al. Effects of metal ions on the hydrolysis of bamboo biomass in 1-butyl-3-methylimidazolium chloride with dilute acid as catalyst[J]. BIORESOURCE TECHNOLOGY,2014,173(0):399-405.
APA Wang, Nan,Zhang, Jie,Wang, Honghui,Li, Qiang,Wei, Sun'an,&Wang, Dan.(2014).Effects of metal ions on the hydrolysis of bamboo biomass in 1-butyl-3-methylimidazolium chloride with dilute acid as catalyst.BIORESOURCE TECHNOLOGY,173(0),399-405.
MLA Wang, Nan,et al."Effects of metal ions on the hydrolysis of bamboo biomass in 1-butyl-3-methylimidazolium chloride with dilute acid as catalyst".BIORESOURCE TECHNOLOGY 173.0(2014):399-405.

入库方式: OAI收割

来源:过程工程研究所

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