中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystallization behaviors of bayerite from sodium chromate alkali solutions

文献类型:期刊论文

作者Wei, Guang-ye1,2; Qu, Jing-kui1; Zheng, Yu-dong2; Qi, Tao1; Guo, Qiang1; Han, Bing-bing1; Zhao, Hong-xin1
刊名TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
出版日期2014-10-01
卷号24期号:10页码:3356-3365
关键词chromate alkali solutions bayerite carbonization crystallization precipitation efficiency
ISSN号1003-6326
其他题名Trans. Nonferrous Met. Soc. China
中文摘要In order to clean production of chromium compounds, it is a critical process to remove aluminates and utilize aluminum compounds from artificial chromate alkali solutions. The effects of Na2CrO4 on the neutralization curve, Al(OH)(3) precipitation efficiency and induction period of bayerite were investigated. The results indicate that the neutralization curve of the artificial chromate alkali solutions shows three distinct regions and its induction period is longer than that of pure sodium aluminate solutions at the same aluminum concentration. And the decreased temperature and volume fraction of CO2 enhance the particle size of bayerite beta-Al(OH)(3). Bayerite composed of agglomerates of rods and cone frustums was obtained from alkali metal chromate solutions with 28.5% CO2 (volume fraction) at temperatures ranging from 50 degrees C to 70 degrees C. Coarse bayerite with particle size (d(50)) from 24.2 mu m to 29.3 mu m extremely has few impurities, which is suitable for comprehensive utilization.
英文摘要In order to clean production of chromium compounds, it is a critical process to remove aluminates and utilize aluminum compounds from artificial chromate alkali solutions. The effects of Na2CrO4 on the neutralization curve, Al(OH)(3) precipitation efficiency and induction period of bayerite were investigated. The results indicate that the neutralization curve of the artificial chromate alkali solutions shows three distinct regions and its induction period is longer than that of pure sodium aluminate solutions at the same aluminum concentration. And the decreased temperature and volume fraction of CO2 enhance the particle size of bayerite beta-Al(OH)(3). Bayerite composed of agglomerates of rods and cone frustums was obtained from alkali metal chromate solutions with 28.5% CO2 (volume fraction) at temperatures ranging from 50 degrees C to 70 degrees C. Coarse bayerite with particle size (d(50)) from 24.2 mu m to 29.3 mu m extremely has few impurities, which is suitable for comprehensive utilization.
WOS标题词Science & Technology ; Technology
类目[WOS]Metallurgy & Metallurgical Engineering
研究领域[WOS]Metallurgy & Metallurgical Engineering
关键词[WOS]ALUMINATE SOLUTIONS ; NEUTRALIZATION ; GIBBSITE ; TRIHYDROXIDE ; NUCLEATION ; HYDROXIDE ; LIQUORS ; GROWTH ; OXIDE ; IONS
收录类别SCI
原文出处http://www.sciencedirect.com/science/article/pii/S1003632614634774
语种英语
WOS记录号WOS:000345542700037
公开日期2015-04-01
源URL[http://ir.ipe.ac.cn/handle/122111/11855]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Univ Sci & Technol, Sch Mat Sci & Engn, Beijing 10083, Peoples R China
推荐引用方式
GB/T 7714
Wei, Guang-ye,Qu, Jing-kui,Zheng, Yu-dong,et al. Crystallization behaviors of bayerite from sodium chromate alkali solutions[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2014,24(10):3356-3365.
APA Wei, Guang-ye.,Qu, Jing-kui.,Zheng, Yu-dong.,Qi, Tao.,Guo, Qiang.,...&Zhao, Hong-xin.(2014).Crystallization behaviors of bayerite from sodium chromate alkali solutions.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,24(10),3356-3365.
MLA Wei, Guang-ye,et al."Crystallization behaviors of bayerite from sodium chromate alkali solutions".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 24.10(2014):3356-3365.

入库方式: OAI收割

来源:过程工程研究所

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