中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of Water on the Density, Viscosity, and CO2 Solubility in Cho line Chloride/Urea

文献类型:期刊论文

作者Xie, Yujiao1; Dong, Haifeng2; Zhang, Suojiang2; Lu, Xiaohua3; Ji, Xiaoyan1
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
出版日期2014-11-01
卷号59期号:11页码:3344-3352
关键词DEEP EUTECTIC SOLVENT PLUS IONIC LIQUID CHOLINE CHLORIDE CARBON-DIOXIDE BINARY-MIXTURES AQUEOUS MIXTURES PHYSICAL-PROPERTIES CAPTURE TEMPERATURE PRESSURES
ISSN号0021-9568
其他题名J. Chem. Eng. Data
中文摘要To study the effect of water on the properties of choline chloride (ChCl)/urea mixtures (1:2 on a molar basis), the density and viscosity of ChCl/urea (1:2) with water were measured at temperatures from 298.15 K to 333.15 K at atmospheric pressure, the CO2 solubility in ChCl/urea (1:2) with water was determined at 308.2 K, 318.2 K, and 328.2 K and at pressures up to 4.5 MPa. The results show that the addition of water significantly decreases the viscosity of ChCl/urea (1:2), whereas the effects on their density and CO2 solubility are much weaker. The CO2 solubility in ChCl/urea (1:2) with water was represented with the Nonrandom-Two-Liquid RedlichKwong (NRTL-RK) model. The excess molar volume and excess molar activation energy were further determined. The CO2 absorption enthalpy was calculated and dominated by the CO2 dissolution enthalpy, and the magnitude of the CO2 dissolution enthalpy decreases with the increase of water content.
英文摘要To study the effect of water on the properties of choline chloride (ChCl)/urea mixtures (1:2 on a molar basis), the density and viscosity of ChCl/urea (1:2) with water were measured at temperatures from 298.15 K to 333.15 K at atmospheric pressure, the CO2 solubility in ChCl/urea (1:2) with water was determined at 308.2 K, 318.2 K, and 328.2 K and at pressures up to 4.5 MPa. The results show that the addition of water significantly decreases the viscosity of ChCl/urea (1:2), whereas the effects on their density and CO2 solubility are much weaker. The CO2 solubility in ChCl/urea (1:2) with water was represented with the Nonrandom-Two-Liquid RedlichKwong (NRTL-RK) model. The excess molar volume and excess molar activation energy were further determined. The CO2 absorption enthalpy was calculated and dominated by the CO2 dissolution enthalpy, and the magnitude of the CO2 dissolution enthalpy decreases with the increase of water content.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]DEEP EUTECTIC SOLVENT ; PLUS IONIC LIQUID ; CHOLINE CHLORIDE ; CARBON-DIOXIDE ; BINARY-MIXTURES ; AQUEOUS MIXTURES ; PHYSICAL-PROPERTIES ; CAPTURE ; TEMPERATURE ; PRESSURES
收录类别SCI
原文出处http://pubs.acs.org/doi/abs/10.1021/je500320c
语种英语
WOS记录号WOS:000344977600007
公开日期2015-04-01
源URL[http://ir.ipe.ac.cn/handle/122111/11858]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Lulea Univ Technol, Div Energy Sci Energy Engn, S-97187 Lulea, Sweden
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
3.Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
推荐引用方式
GB/T 7714
Xie, Yujiao,Dong, Haifeng,Zhang, Suojiang,et al. Effect of Water on the Density, Viscosity, and CO2 Solubility in Cho line Chloride/Urea[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2014,59(11):3344-3352.
APA Xie, Yujiao,Dong, Haifeng,Zhang, Suojiang,Lu, Xiaohua,&Ji, Xiaoyan.(2014).Effect of Water on the Density, Viscosity, and CO2 Solubility in Cho line Chloride/Urea.JOURNAL OF CHEMICAL AND ENGINEERING DATA,59(11),3344-3352.
MLA Xie, Yujiao,et al."Effect of Water on the Density, Viscosity, and CO2 Solubility in Cho line Chloride/Urea".JOURNAL OF CHEMICAL AND ENGINEERING DATA 59.11(2014):3344-3352.

入库方式: OAI收割

来源:过程工程研究所

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