Partially Reduced CuO Nanoparticles as Multicomponent Cu-Based Catalysts for the Rochow Reaction
文献类型：期刊论文
| 作者 | Liu, Wuyuan1,2; Jia, Lihua1; Wang, Yingli2; Song, Lianying2; Zhu, Yongxia2; Chen, Xin2; Zhong, Ziyi3; Su, Fabing2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2013-05-22 |
| 卷号 | 52期号:20页码:6662-6668 |
| ISSN号 | 0888-5885 |
| 英文摘要 | We report the application of partially reduced CuO nanoparticles as Cu-based catalysts for dimethyldichlorosilane (M2) synthesis via the Rochow reaction. The CuO nanoparticles (50-100 nm) were synthesized by a simple precipitation method and partially reduced in a H-2/N-2 mixture gas to obtain the Cu-based catalyst containing different Cu species of CuO, Cu2O, and Cu. It was found that the composition of the samples could be tailored by varying the volume ratio of H-2/N-2 at the given reduction temperature and time. Compared to the synthesized CuO and Cu nanoparticles, as well as the commercial CuO microparticles, these multicomponent Cu-based catalysts, particularly for the CuO-Cu2O-Cu catalyst, showed much higher M2 selectivity and Si conversion in the Rochow reaction. The enhanced catalytic performance is attributed to the smaller particle size and the synergistic effect among the different components. The work would help to develop novel ternary Cu-based catalysts for organosilane synthesis. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | DIMETHYLDICHLOROSILANE SYNTHESIS ; MICROSPHERES ; REDUCTION ; PROMOTERS ; PHASE ; NANOCRYSTALS ; PERFORMANCE ; MECHANISM ; DIFFUSION ; OXIDATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000319551400006 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13317]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Heilongjiang Pr, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.ASTAR, Inst Chem Engn & Sci, Jurong Isl 627833, Singapore |
| 推荐引用方式 GB/T 7714 | Liu, Wuyuan,Jia, Lihua,Wang, Yingli,et al. Partially Reduced CuO Nanoparticles as Multicomponent Cu-Based Catalysts for the Rochow Reaction[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(20):6662-6668. |
| APA | Liu, Wuyuan.,Jia, Lihua.,Wang, Yingli.,Song, Lianying.,Zhu, Yongxia.,...&Su, Fabing.(2013).Partially Reduced CuO Nanoparticles as Multicomponent Cu-Based Catalysts for the Rochow Reaction.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(20),6662-6668. |
| MLA | Liu, Wuyuan,et al."Partially Reduced CuO Nanoparticles as Multicomponent Cu-Based Catalysts for the Rochow Reaction".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.20(2013):6662-6668. |
入库方式： OAI收割
来源：过程工程研究所
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