Efficiently trapping asphaltene-type materials from direct coal liquefaction residue using alkylsulfate-based ionic liquids
文献类型:期刊论文
作者 | Bai, Lu1,2; Nie, Yi1; Huang, Jincheng1; Li, Yi1; Dong, Haifeng1; Zhang, Xiangping1 |
刊名 | FUEL
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出版日期 | 2013-10-01 |
卷号 | 112期号:0页码:289-294 |
关键词 | Ionic liquids Extraction Asphaltene Direct coal liquefaction residue |
英文摘要 | Alkylsulfate-based ionic liquids (ILs) were synthesized and used as solid-liquid separation solvents to extract asphaltene-type materials from direct coal liquefaction residue (DCLR). Among the ILs employed, tetraethylammonium ethylsulfate ([E4N][ESO4]) was proved to be a potential solvent for trapping asphaltene-type materials from DCLR due to the higher extraction yield and the lower H/C atomic ratio of the extract. N-methyl-2-pyrrolidone (NMP) was added to reduce the viscosity of [E4N][ESO4]. It also increased the extraction yield and decreased H/C atomic ratio of the asphaltene-type materials. The mechanism of extraction might be concluded that the interactions are formed between ILs or [E4N][ESO4]/NMP mixed solvents and asphaltene-type materials, which disturbs the interactions between DCLR and leads to the dissolution of asphaltene-type materials into solvents. The obtained asphaltene-type materials possessed low H/C atomic ratios, high aromaticities, no ashes and no quinoline insolubles, which meet the requirements of preparing carbon materials. (C) 2013 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Energy & Fuels ; Engineering, Chemical |
研究领域[WOS] | Energy & Fuels ; Engineering |
关键词[WOS] | AROMATIC-HYDROCARBONS ; MIXED-SOLVENT ; EXTRACTION ; DESULFURIZATION ; SEPARATION ; DISPERSION ; SULFATE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000321735400036 |
公开日期 | 2015-05-27 |
源URL | [http://ir.ipe.ac.cn/handle/122111/13352] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Bai, Lu,Nie, Yi,Huang, Jincheng,et al. Efficiently trapping asphaltene-type materials from direct coal liquefaction residue using alkylsulfate-based ionic liquids[J]. FUEL,2013,112(0):289-294. |
APA | Bai, Lu,Nie, Yi,Huang, Jincheng,Li, Yi,Dong, Haifeng,&Zhang, Xiangping.(2013).Efficiently trapping asphaltene-type materials from direct coal liquefaction residue using alkylsulfate-based ionic liquids.FUEL,112(0),289-294. |
MLA | Bai, Lu,et al."Efficiently trapping asphaltene-type materials from direct coal liquefaction residue using alkylsulfate-based ionic liquids".FUEL 112.0(2013):289-294. |
入库方式: OAI收割
来源:过程工程研究所
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