Removal of zirconium from hydrous titanium dioxide
文献类型:期刊论文
作者 | Ma, Xue-qin1,2,3; Liu, Ya-hui1,2; Chu, Jing-long1,2; Li, Jie1,2; Xue, Tian-yan1,2; Wang, Li-na1,2; Qi, Tao1,2 |
刊名 | INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
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出版日期 | 2013 |
卷号 | 20期号:1页码:1-8 |
关键词 | zirconium titanium dioxide removal density functional theory microstructure adsorption |
英文摘要 | A method was proposed for removing zirconium (Zr) from hydrous titanium dioxide (HTD) by the NaF solution. The effects of main parameters, i.e. pH values, NaF dosage, temperature and retention time, on the removal of zirconium were studied. The optimal conditions were found as the following: pH value, <5.5; molar ratio of NaF to TiO2, 0.6; retention time, 80 min; and temperature, 80 degrees C. The removal rate of Zr under the optimized conditions was above 87.7%. The adsorption energy of the preferential absorption of hydrofluoric acid for Zr(OH)(2)SO4(OH2) on the (001) crystal surface of HTD was determined by theoretical calculation. The possible mechanism of the removal process was also discussed. |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
类目[WOS] | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
研究领域[WOS] | Materials Science ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
关键词[WOS] | SODIUM-HYDROXIDE ; AB-INITIO ; TIO2 ; ACID ; DECOMPOSITION ; MOLECULES ; ANATASE ; PIGMENT ; SLAG |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000313198200001 |
公开日期 | 2015-05-27 |
源URL | [http://ir.ipe.ac.cn/handle/122111/13378] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Xue-qin,Liu, Ya-hui,Chu, Jing-long,et al. Removal of zirconium from hydrous titanium dioxide[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,2013,20(1):1-8. |
APA | Ma, Xue-qin.,Liu, Ya-hui.,Chu, Jing-long.,Li, Jie.,Xue, Tian-yan.,...&Qi, Tao.(2013).Removal of zirconium from hydrous titanium dioxide.INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,20(1),1-8. |
MLA | Ma, Xue-qin,et al."Removal of zirconium from hydrous titanium dioxide".INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS 20.1(2013):1-8. |
入库方式: OAI收割
来源:过程工程研究所
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