中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Removal of zirconium from hydrous titanium dioxide

文献类型:期刊论文

作者Ma, Xue-qin1,2,3; Liu, Ya-hui1,2; Chu, Jing-long1,2; Li, Jie1,2; Xue, Tian-yan1,2; Wang, Li-na1,2; Qi, Tao1,2
刊名INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
出版日期2013
卷号20期号:1页码:1-8
关键词zirconium titanium dioxide removal density functional theory microstructure adsorption
英文摘要A method was proposed for removing zirconium (Zr) from hydrous titanium dioxide (HTD) by the NaF solution. The effects of main parameters, i.e. pH values, NaF dosage, temperature and retention time, on the removal of zirconium were studied. The optimal conditions were found as the following: pH value, <5.5; molar ratio of NaF to TiO2, 0.6; retention time, 80 min; and temperature, 80 degrees C. The removal rate of Zr under the optimized conditions was above 87.7%. The adsorption energy of the preferential absorption of hydrofluoric acid for Zr(OH)(2)SO4(OH2) on the (001) crystal surface of HTD was determined by theoretical calculation. The possible mechanism of the removal process was also discussed.
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing
研究领域[WOS]Materials Science ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing
关键词[WOS]SODIUM-HYDROXIDE ; AB-INITIO ; TIO2 ; ACID ; DECOMPOSITION ; MOLECULES ; ANATASE ; PIGMENT ; SLAG
收录类别SCI
语种英语
WOS记录号WOS:000313198200001
公开日期2015-05-27
源URL[http://ir.ipe.ac.cn/handle/122111/13378]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ma, Xue-qin,Liu, Ya-hui,Chu, Jing-long,et al. Removal of zirconium from hydrous titanium dioxide[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,2013,20(1):1-8.
APA Ma, Xue-qin.,Liu, Ya-hui.,Chu, Jing-long.,Li, Jie.,Xue, Tian-yan.,...&Qi, Tao.(2013).Removal of zirconium from hydrous titanium dioxide.INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,20(1),1-8.
MLA Ma, Xue-qin,et al."Removal of zirconium from hydrous titanium dioxide".INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS 20.1(2013):1-8.

入库方式: OAI收割

来源:过程工程研究所

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