Influence of FeCl3 on radiation stability of ionic liquid BmimCl
文献类型：期刊论文
| 作者 | Huang Lei1,2; Huang Wei1; Fu HaiYing1; Wu GuoZhong1; Guo ZhiJun2; Wu WangSuo2; Chen ShiMou3 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2013-04-01 |
| 卷号 | 58期号:10页码:1150-1155 |
| 关键词 | radiation ionic liquid FeCl3 BmimFeCl(4) solvated electron |
| ISSN号 | 1001-6538 |
| 英文摘要 | This study investigates the effect FeCl3 on the radiation stability of the ionic liquid, 1-butyl-3-methylimidazolium chloride (BmimCl) over a wide dose range of 0 to 1000 kGy under gamma-ray radiation. The ionic liquid species, BmimFeCl(4), was formed by adding FeCl3 into BmimCl. The results showed that the presence of FeCl4 (-) significantly improved the radiation resistance of BmimCl, wherein the effect was more pronounced at higher FeCl4 (-) content. Meanwhile, under irradiation, Fe(II) was generated from Fe(III), which was reduced by solvated electron. In addition, the concentration of Fe(II) increased with low level of absorbed dose, but leveled off at higher doses. Moreover, the radiation yield of the solvated electrons of BmimCl was further estimated at approximately 0.358 +/- 0.01 mu mol/J in BmimCl-7 mol% FeCl3 system. |
| WOS标题词 | Science & Technology |
| 类目[WOS] | Multidisciplinary Sciences |
| 研究领域[WOS] | Science & Technology - Other Topics |
| 关键词[WOS] | ROOM-TEMPERATURE ; SOLVATED ELECTRON ; GAMMA-RADIATION ; RADIOLYSIS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000316954900009 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13408]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China 2.Lanzhou Univ, Sch Nucl Sci & Technol, Radiochem Lab, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang Lei,Huang Wei,Fu HaiYing,et al. Influence of FeCl3 on radiation stability of ionic liquid BmimCl[J]. CHINESE SCIENCE BULLETIN,2013,58(10):1150-1155. |
| APA | Huang Lei.,Huang Wei.,Fu HaiYing.,Wu GuoZhong.,Guo ZhiJun.,...&Chen ShiMou.(2013).Influence of FeCl3 on radiation stability of ionic liquid BmimCl.CHINESE SCIENCE BULLETIN,58(10),1150-1155. |
| MLA | Huang Lei,et al."Influence of FeCl3 on radiation stability of ionic liquid BmimCl".CHINESE SCIENCE BULLETIN 58.10(2013):1150-1155. |
入库方式： OAI收割
来源：过程工程研究所
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