Template-Free Synthesis of Mesoporous Hollow CuO Microspheres as Anode Materials for Li-Ion Batteries
文献类型：期刊论文
| 作者 | Zhang, Zailei1,2; Che, Hongwei2; Sun, Jin1; She, Xilin1; Chen, Han2; Su, Fabing2 |
| 刊名 | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 13期号:2页码:1530-1534 |
| 关键词 | CuO Microspheres Mesoporous Hollow Anode Materials Li-Ion Batteries |
| 英文摘要 | We report the preparation and characterization of mesoporous hollow CuO (MPH-CuO) microspheres by thermal decomposition of hollow copper oxalate microspheres synthesized via the reaction of ammonium oxalate and copper chloride without using any template. The sample was characterized by Nitrogen adsorption, X-ray diffraction, transmission electron microscopy, and scanning electron microscopy. The electrochemical performance of MPH-CuO microspheres as anode materials in Li-ion batteries was evaluated. It was found that the MPH-CuO microspheres possessed an average diameter of 2.5 mu m, a pore size of 17.5 nnn, and a BET surface area of 15.2 m(2)/g. Their shells were composed of CuO nanocrystals with a size, of 17.9 nm. Compared with the dense CuO microspheres, the obtained MPH-CuO shows an enhanced electrochemical performance with a higher capacity of 599.4 mAh/g and a better cyclability (484 mAh/g after 15 cycles) because of its mesoporous hollow structure that provides quick intercalation and large accommodation of lithium ions together with short diffusion distance for lithium ions, suggesting a potential application in Li-ion batteries. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 关键词[WOS] | ELECTROCHEMICAL PERFORMANCE ; ELECTRODE MATERIALS ; HARD TEMPLATES ; LITHIUM ; FABRICATION ; COPPER ; MICRO/NANOSTRUCTURES ; SIZE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318254500172 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13423]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zailei,Che, Hongwei,Sun, Jin,et al. Template-Free Synthesis of Mesoporous Hollow CuO Microspheres as Anode Materials for Li-Ion Batteries[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2013,13(2):1530-1534. |
| APA | Zhang, Zailei,Che, Hongwei,Sun, Jin,She, Xilin,Chen, Han,&Su, Fabing.(2013).Template-Free Synthesis of Mesoporous Hollow CuO Microspheres as Anode Materials for Li-Ion Batteries.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,13(2),1530-1534. |
| MLA | Zhang, Zailei,et al."Template-Free Synthesis of Mesoporous Hollow CuO Microspheres as Anode Materials for Li-Ion Batteries".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 13.2(2013):1530-1534. |
入库方式： OAI收割
来源：过程工程研究所
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