Kinetic Study on the Novel Efficient Clean Decomposition of Methyl N-Phenyl Carbamate to Phenyl Isocyanate
文献类型：期刊论文
| 作者 | Zhu, Ganyu1,2; Li, Huiquan1; Cao, Yan1; Liu, Haitao1; Li, Xintao1,2; Chen, Jiaqiang1; Tang, Qing1 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2013-03-27 |
| 卷号 | 52期号:12页码:4450-4454 |
| 英文摘要 | This study presents a clean, novel, and highly efficient system for the decomposition of methyl N-phenyl carbamate (MPC) to phenyl isocyanate (PI). MPC conversion of high as 89% and PI selectivity of almost 100% were obtained using chlorobenzene solvent under high pressure without any catalyst. The effects of temperature and time on the conversion of MPC were investigated, and the apparent kinetics model of MPC decomposition reaction was established. Results indicate that the decomposition of MPC is a pseudo-first-order reaction with Arrhenius parameters of E-a = 71.28 kJ/mol and A = 2.74 x 10(5) min(-1), and the model correlated well with experimental data. This study provides not only a new and clean system for the highly efficient production of PI, but also a guide for the design of reactors in the isocyanate industry. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | DIMETHYL CARBONATE ; CATALYSTS ; CARBONYLATION ; METHANOL ; ROUTE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317031700010 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13427]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Ganyu,Li, Huiquan,Cao, Yan,et al. Kinetic Study on the Novel Efficient Clean Decomposition of Methyl N-Phenyl Carbamate to Phenyl Isocyanate[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(12):4450-4454. |
| APA | Zhu, Ganyu.,Li, Huiquan.,Cao, Yan.,Liu, Haitao.,Li, Xintao.,...&Tang, Qing.(2013).Kinetic Study on the Novel Efficient Clean Decomposition of Methyl N-Phenyl Carbamate to Phenyl Isocyanate.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(12),4450-4454. |
| MLA | Zhu, Ganyu,et al."Kinetic Study on the Novel Efficient Clean Decomposition of Methyl N-Phenyl Carbamate to Phenyl Isocyanate".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.12(2013):4450-4454. |
入库方式： OAI收割
来源：过程工程研究所
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