Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate
文献类型：期刊论文
| 作者 | Yu, Bing1,2; Diao, Zhen-Feng1,2; Guo, Chun-Xiang1,2; Zhong, Chun-Lai1,2; He, Liang-Nian1,2; Zhao, Ya-Nan1,2; Song, Qing-Wen1,2; Liu, An-Hua1,2; Wang, Jin-Quan3 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:9页码:2401-2407 |
| 英文摘要 | The CuI-catalyzed carboxylation of terminal alkynes with CO2 and alkyl halides using ethylene carbonate as the solvent under mild conditions was studied. DFT calculations reveal that the energy barrier for CO2 insertion into the sp-hybridized Cu-C bond could be reduced by employing ethylene carbonate as the solvent. Notably, the procedure was conducted under ambient CO2 pressure without any external ligands. A broad range of substrates with electron-withdrawing groups or electron-donating groups gave the corresponding products in reasonable yields. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | C-H BONDS ; METAL-CATALYZED CARBOXYLATION ; CARBENE COPPER(I) COMPLEXES ; ALKENYLBORONIC ESTERS ; ORGANIC CARBONATES ; DIMETHYL CARBONATE ; CYCLIC CARBONATES ; FRIENDLY SOLVENT ; ALLYL STANNANES ; DIOXIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323179000014 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13461]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China 2.Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Bing,Diao, Zhen-Feng,Guo, Chun-Xiang,et al. Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate[J]. GREEN CHEMISTRY,2013,15(9):2401-2407. |
| APA | Yu, Bing.,Diao, Zhen-Feng.,Guo, Chun-Xiang.,Zhong, Chun-Lai.,He, Liang-Nian.,...&Wang, Jin-Quan.(2013).Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate.GREEN CHEMISTRY,15(9),2401-2407. |
| MLA | Yu, Bing,et al."Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate".GREEN CHEMISTRY 15.9(2013):2401-2407. |
入库方式： OAI收割
来源：过程工程研究所
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