Ionic liquid based three-liquid-phase partitioning and one-step separation of Pt (IV), Pd (II) and Rh (III)
文献类型：期刊论文
| 作者 | Zhang, Chao1,2,3; Huang, Kun1; Yu, Pinhua1,2,3; Liu, Huizhou1 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2013-04-19 |
| 卷号 | 108期号:0页码:166-173 |
| 关键词 | Ionic liquids Three-liquid-phase extraction (TLPE) Platinum group metals (PGMs) |
| 英文摘要 | The present work reports an interesting phenomena that the addition of hydrophobic ionic liquid, [C(4-)mim]PF6, into the oil-water two phase system of diisopentyl sulfide (S201)-nonane organic solutions and hydrochloric acid aqueous solutions containing Pt (IV), Pd (II) and Rh (III) chloric-complexing anions could induce the formation of a stable liquid-liquid-liquid three layered liquids coexisting medium for extraction and one-step separation of platinum, palladium and rhodium. The influences of H+ and Cl- concentrations in equilibrating aqueous solutions, the initial Pt (IV) concentration, the volume ratio of added [C(4)mim][PF6] to hydrochloric acid aqueous solution and the different salt ions in equilibrating aqueous solutions on the three-liquid-phase partitioning behaviors of three platinum metal ions were evaluated. The transferring of PtCl62- into the [C(4)mim]PF6 bottom phase in TLPS was proposed to be according with an anion exchange between PtCl62- and PF6- in ionic liquid. Therefore, the separated ionic liquid phase is not the solvent of organic extractants, but provides an extended separation capacity than the literature reported ionic liquid based two-phase extraction systems. The present work indicated that this ionic liquid based three-liquid system can be used to separate multi-metal coexisting solutions. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | ACID SOLUTIONS ; METAL-IONS ; EXTRACTION ; PALLADIUM ; PLATINUM ; RECOVERY ; PYRIDINECARBOXAMIDES ; CHEMISTRY ; CATALYSIS ; SOLVENTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317887200023 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13587]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Chao,Huang, Kun,Yu, Pinhua,et al. Ionic liquid based three-liquid-phase partitioning and one-step separation of Pt (IV), Pd (II) and Rh (III)[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2013,108(0):166-173. |
| APA | Zhang, Chao,Huang, Kun,Yu, Pinhua,&Liu, Huizhou.(2013).Ionic liquid based three-liquid-phase partitioning and one-step separation of Pt (IV), Pd (II) and Rh (III).SEPARATION AND PURIFICATION TECHNOLOGY,108(0),166-173. |
| MLA | Zhang, Chao,et al."Ionic liquid based three-liquid-phase partitioning and one-step separation of Pt (IV), Pd (II) and Rh (III)".SEPARATION AND PURIFICATION TECHNOLOGY 108.0(2013):166-173. |
入库方式： OAI收割
来源：过程工程研究所
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