Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems
文献类型：期刊论文
| 作者 | Sun, Zhicheng1,2; She, Yuanbin1; Cao, Meijuan1; Zhou, Qing2; Lu, Xingmei2; Zhang, Suojiang2 |
| 刊名 | ARKIVOC
 |
| 出版日期 | 2013 |
| 期号 | 0页码:389-400 |
| 关键词 | Porphyrin synthesis mixed solvents oxidant |
| 英文摘要 | An efficient synthetic method of substituted meso-tetraphenylporphyrins with better isolated yields was proposed by using propionic acid, valeric acid and m-nitrotoluene as mixed-solvent systems. The porphyrin yields in mixed solvent systems were obviously higher than those in the single propionic acid or valeric acid as solvents. The further investigation showed that the acidity, polarity, viscosity and the property of oxidant played an important role to the synthesis of porphyrin. Compared with other oxidants, m-nitrotoluene as an excellent oxidant could completely transform tetraphenylporphyrinogen to tetraphenylporphyrin. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | MESOSUBSTITUTED CORROLES ; PORPHYRINS ; OXIDATION ; LIGAND ; ROTHEMUND ; CATALYSTS ; PYRROLE ; 2-STEP ; SALTS ; AIR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000324461400027 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13603]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Beijing Univ Technol, Inst Green Chem & Fine Chem, Beijing 100124, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Zhicheng,She, Yuanbin,Cao, Meijuan,et al. Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems[J]. ARKIVOC,2013(0):389-400. |
| APA | Sun, Zhicheng,She, Yuanbin,Cao, Meijuan,Zhou, Qing,Lu, Xingmei,&Zhang, Suojiang.(2013).Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems.ARKIVOC(0),389-400. |
| MLA | Sun, Zhicheng,et al."Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems".ARKIVOC .0(2013):389-400. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。