Template-free solvothermal synthesis of hierarchical boehmite hollow microspheres with strong affinity toward organic pollutants in water
文献类型：期刊论文
| 作者 | Cai, Weiquan1; Chen, Shuanggui1; Yu, Jiaguo2; Hu, Yuzhen1; Dang, Chengxiong1; Ma, Shuhua3 |
| 刊名 | MATERIALS CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2013-02-15 |
| 卷号 | 138期号:1页码:167-173 |
| 关键词 | Inorganic compounds Nanostructures Chemical synthesis Microstructure Adsorption |
| 英文摘要 | Three-dimensional hierarchical boehmite hollow microspheres with a very high yield at low cost were successfully synthesized via a one-pot template-free solvothermal route using aluminum chloride hexahydrate as precursor in a mixed ethanol-water solution with assistance of trisodium citrate. The as-synthesized products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption/desorption techniques. The results show that Cl- and addition amount of trisodium citrate have significant effect on the morphologies of the resultant products, and 6-8 mmol of trisodium citrate is optimal for the synthesis of boehmite hollow microspheres assembled from randomly interconnecting and aligned nanorods with solvothermal time no less than 15 h. A synergistic mediation mechanism of citrate ions and Cl- to form boehmite hollow spheres via self-assembly morphology evolution was proposed based on the experimental results. Interestingly, the typical boehmite hollow microspheres with a surface area of 102 m(2) g(-1), pore volume of 0.37 cm(3) g(-1), and the average pore size of 14.6 nm show superb adsorption properties for Congo red with maximum capacity of 114.7 mg g(-1) which is higher than that of a commercial boehmite. This simple synthetic route is a very promising way for the design and synthesis of new functional hierarchical nanostructured materials with desired adsorptive properties. (C) 2012 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Materials Science, Multidisciplinary |
| 研究领域[WOS] | Materials Science |
| 关键词[WOS] | HYDROTHERMAL SYNTHESIS ; CONGO RED ; ADSORPTION ; ALOOH ; OXIDE ; TRANSFORMATION ; CAPABILITY ; SURFACTANT ; CORE/SHELL ; REMOVAL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000316241500022 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13619]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Wuhan Univ Technol, Sch Chem Engn, Wuhan 430070, Peoples R China 2.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Weiquan,Chen, Shuanggui,Yu, Jiaguo,et al. Template-free solvothermal synthesis of hierarchical boehmite hollow microspheres with strong affinity toward organic pollutants in water[J]. MATERIALS CHEMISTRY AND PHYSICS,2013,138(1):167-173. |
| APA | Cai, Weiquan,Chen, Shuanggui,Yu, Jiaguo,Hu, Yuzhen,Dang, Chengxiong,&Ma, Shuhua.(2013).Template-free solvothermal synthesis of hierarchical boehmite hollow microspheres with strong affinity toward organic pollutants in water.MATERIALS CHEMISTRY AND PHYSICS,138(1),167-173. |
| MLA | Cai, Weiquan,et al."Template-free solvothermal synthesis of hierarchical boehmite hollow microspheres with strong affinity toward organic pollutants in water".MATERIALS CHEMISTRY AND PHYSICS 138.1(2013):167-173. |
入库方式： OAI收割
来源：过程工程研究所
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