Ionic liquid enhanced alkylation of iso-butane and 1-butene
文献类型：期刊论文
| 作者 | Cui, Peng1,2; Zhao, Guoying2; Ren, Hailing1,2; Huang, Jun1; Zhang, Suojiang2 |
| 刊名 | CATALYSIS TODAY
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 200期号:0页码:30-35 |
| 关键词 | Ionic liquids Alkylation iso-Butane Butene Triflic acid |
| 英文摘要 | The alkylation of iso-butane with 1-butene was catalyzed by triflic acid (TFOH) coupled with a series of protic ammonium-based ionic liquids (AMILs), and the addition of the AMILs dramatically enhanced the efficiency of TFOH for the alkylation reaction. Up to 85.1% trimethylpentanes (TMP) selectivity and 98 research octane number (RON) were achieved with the optimized TFOH/AMIL catalyst ( 75 vol.% triflic acid and 25 vol.% triethylammonium hydrogen sulfate), which were much better than that with the commercial H2SO4 catalyst (65% TMP selectivity, 97 RON) and pure triflic acid. The addition of AMILs increased the I/O ratio dissolved in the catalyst system and adjusted the acidity of the TFOH/AMILs catalyst system, which were highly beneficial to the alkylation reaction and resulted in high TMP selectivity and high RON. (c) 2012 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | SOLID ACID CATALYSTS ; ISOBUTANE ALKYLATION ; 2-BUTENE ; SOLUBILITIES ; DIFFUSIVITY ; BUTENE ; MEDIA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311938100006 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13620]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn,Beijing Key Lab Ion Liquids Clean, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Peng,Zhao, Guoying,Ren, Hailing,et al. Ionic liquid enhanced alkylation of iso-butane and 1-butene[J]. CATALYSIS TODAY,2013,200(0):30-35. |
| APA | Cui, Peng,Zhao, Guoying,Ren, Hailing,Huang, Jun,&Zhang, Suojiang.(2013).Ionic liquid enhanced alkylation of iso-butane and 1-butene.CATALYSIS TODAY,200(0),30-35. |
| MLA | Cui, Peng,et al."Ionic liquid enhanced alkylation of iso-butane and 1-butene".CATALYSIS TODAY 200.0(2013):30-35. |
入库方式： OAI收割
来源：过程工程研究所
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