Ethylene hydroformylation in imidazolium-based ionic liquids catalyzed by rhodium-phosphine complexes
文献类型：期刊论文
| 作者 | Diao, Yanyan1; Li, Jing1; Wang, Ling1; Yang, Pu1; Yan, Ruiyi1; Jiang, Li1,2; Zhang, Heng1,3; Zhang, Suojiang1 |
| 刊名 | CATALYSIS TODAY
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 200期号:0页码:54-62 |
| 关键词 | Hydroformylation Ionic liquids Ethylene Rh catalyst |
| 英文摘要 | In this research, the catalytic activity of a rhodium-based (Rh) catalyst with imidazolium-based ionic liquids (IBILs) as solvents for ethylene hydroformylation was studied. The structures of IBILs had an important influence on the activity and stability of the Rh catalyst. The IBILs with longer cation side chains, which were the strong steric hindrances around the Rh catalyst, were more unfavorable for the catalytic activity. The turnover frequency (TOF) of the Rh catalyst was 10627 h(-1) when [Bmim][BF4] was used as solvent. The activity of the Rh complexes in the ionic liquid is better than they do in toluene. We used electrospray ionization mass spectrometry to characterize the catalyst after the reaction and found that [Bmim](+) acts as a ligand of the Rh catalyst to form a new active catalytic site [Rh(CO)(PPh3)(2)(Bmim)(BF4)](+) through the coordination of the Rh atom with the imidazole-2-C group of [Bmim][BF4], and it was essential for the stabilization of the Rh catalyst and prevented the formation of low-active Rh clusters. In addition, the catalyst recycling test showed that the Rh catalyst could be reused with [Bmim][BF4] as solvent without obvious loss of catalytic activity. (c) 2012 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | BIPHASIC HYDROFORMYLATION ; SALTS ; SOLVENTS ; ALKENES ; HEXAFLUOROPHOSPHATE ; HYDROGENATION ; ISOMERIZATION ; MECHANISM ; LIGANDS ; OCTENES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311938100010 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13641]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Peoples R China |
| 推荐引用方式 GB/T 7714 | Diao, Yanyan,Li, Jing,Wang, Ling,et al. Ethylene hydroformylation in imidazolium-based ionic liquids catalyzed by rhodium-phosphine complexes[J]. CATALYSIS TODAY,2013,200(0):54-62. |
| APA | Diao, Yanyan.,Li, Jing.,Wang, Ling.,Yang, Pu.,Yan, Ruiyi.,...&Zhang, Suojiang.(2013).Ethylene hydroformylation in imidazolium-based ionic liquids catalyzed by rhodium-phosphine complexes.CATALYSIS TODAY,200(0),54-62. |
| MLA | Diao, Yanyan,et al."Ethylene hydroformylation in imidazolium-based ionic liquids catalyzed by rhodium-phosphine complexes".CATALYSIS TODAY 200.0(2013):54-62. |
入库方式： OAI收割
来源：过程工程研究所
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