Novel Process for Titanium Dioxide Production from Titanium Slag: NaOH-KOH Binary Molten Salt Roasting and Water Leaching
文献类型：期刊论文
| 作者 | Wang, Dong1,2,3; Chu, Jinglong2,3; Liu, Yahui2,3; Li, Jie2,3; Xue, Tianyan2,3; Wang, Weijing1,2,3; Qi, Tao2,3 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2013-11-13 |
| 卷号 | 52期号:45页码:15756-15762 |
| 英文摘要 | Titanium dioxide (TiO2) has been widely used as pigment in paints, fillers for plastic and paper, coatings, adsorbents, cosmetics, catalysts, and gas sensors. A novel process for TiO2 production has been developed by the Institute of Process Engineering. This work develops the novel process by using the NaOH/KOH binary molten salt (50 mol % NaOH, 50 mol % KOH) instead of NaOH molten salt. Under conditions of temperature 350 degrees C and mixed alkali-to-titanium slag ratio 1.4:1, the titanium conversion ratio obtained is >98% with reaction time around 90 min. The kinetics investigation indicates that the decomposition of titanium slag is controlled by mass diffusion in thed residual layer and the apparent activation energy is 43.1 kJ/mol. 98% of KOH and 86% of NaOH can be recycled by a water leaching process. On the basis of the experimental results, a flow sheet was developed and tested, and the content of TiO2 obtained in the product reached 99.5%. As the NaOH/KOH binary molten salt system provides a liquid as relatively low temperature, the energy consumption of this technology may probably be lower than that of the existing one. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | SODIUM-HYDROXIDE ; DECOMPOSITION ; ILMENITE ; PRESSURE ; CHROMITE ; SYSTEM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000327103300007 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13649]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Dong,Chu, Jinglong,Liu, Yahui,et al. Novel Process for Titanium Dioxide Production from Titanium Slag: NaOH-KOH Binary Molten Salt Roasting and Water Leaching[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(45):15756-15762. |
| APA | Wang, Dong.,Chu, Jinglong.,Liu, Yahui.,Li, Jie.,Xue, Tianyan.,...&Qi, Tao.(2013).Novel Process for Titanium Dioxide Production from Titanium Slag: NaOH-KOH Binary Molten Salt Roasting and Water Leaching.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(45),15756-15762. |
| MLA | Wang, Dong,et al."Novel Process for Titanium Dioxide Production from Titanium Slag: NaOH-KOH Binary Molten Salt Roasting and Water Leaching".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.45(2013):15756-15762. |
入库方式： OAI收割
来源：过程工程研究所
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