Hydrogenolysis of cellulose to C4-C7 alcohols over bi-functional CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction
文献类型：期刊论文
| 作者 | Wu, Yanhua1,2; Gu, Fangna1; Xu, Guangwen1; Zhong, Ziyi3; Su, Fabing1 |
| 刊名 | BIORESOURCE TECHNOLOGY
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 137期号:0页码:311-317 |
| 关键词 | Hydrogenolysis Cellulose Methanol C4-C7 alcohols CuO-based bi-functional catalyst |
| 英文摘要 | This work demonstrates the efficient hydrogenolysis of cellulose to C4-C7 alcohols and gas products (reaction 1) by coupling it with the reforming reaction of methanol (reaction 2) over bi-functional CuO-based catalysts. In this process, the CuO-based catalysts catalyze both the reactions 1 and 2, and the in situ regenerated H-2 in the reaction 2 is used for the reaction 1. A series of CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts were prepared by the co-precipitation method. Among these catalysts, CuO-ZnO/Al2O3 exhibited the highest activity to generate a high cellulose conversion of 88% and a high C4-C7 alcohols content above 95% in the liquid products. The CuO-ZnO/Al2O3 catalyst was stable under the reaction conditions and reusable after 4 runs. This work provides a cost-effective route to convert abundant renewable cellulose to liquid fuels. (C) 2013 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Technology |
| 类目[WOS] | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 研究领域[WOS] | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 关键词[WOS] | GAS SHIFT REACTION ; CHEMICAL CONVERSION ; FAST PYROLYSIS ; LIQUID FUELS ; POLYOLS ; BIOMASS ; WATER ; HYDROCARBONS ; TEMPERATURE ; HYDROLYSIS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000319645600041 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13657]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore |
| 推荐引用方式 GB/T 7714 | Wu, Yanhua,Gu, Fangna,Xu, Guangwen,et al. Hydrogenolysis of cellulose to C4-C7 alcohols over bi-functional CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction[J]. BIORESOURCE TECHNOLOGY,2013,137(0):311-317. |
| APA | Wu, Yanhua,Gu, Fangna,Xu, Guangwen,Zhong, Ziyi,&Su, Fabing.(2013).Hydrogenolysis of cellulose to C4-C7 alcohols over bi-functional CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction.BIORESOURCE TECHNOLOGY,137(0),311-317. |
| MLA | Wu, Yanhua,et al."Hydrogenolysis of cellulose to C4-C7 alcohols over bi-functional CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction".BIORESOURCE TECHNOLOGY 137.0(2013):311-317. |
入库方式： OAI收割
来源：过程工程研究所
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