Synthesis of bio-based polyurethanes from epoxidized soybean oil and isopropanolamine
文献类型：期刊论文
| 作者 | Miao, Shida1; Zhang, Songping1; Su, Zhiguo1; Wang, Ping2 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2013-02-05 |
| 卷号 | 127期号:3页码:1929-1936 |
| 关键词 | epoxidized soybean oil isopropanolamine polyurethanes NMR synthesis |
| 英文摘要 | Epoxidized soybean oil (ESO) and isopropanolamine were used to synthesize a new polyol mixture for preparation of bio-based polyurethanes. The chemical synthetic route for reaction of ESO with isopropanolamine was analyzed by H-1-NMR. The results suggested that both ester groups and epoxy groups in ESO had reacted with amino group of isopropanolamine through simultaneous ring-opening and amidation reactions. Epoxy groups in various situations exhibited different reactivity, and the unreacted epoxy groups were further opened by hydrochloric acid. The synthesized polyol mixture had high hydroxyl number of 317.0 mg KOH/g. A series of polyurethanes were prepared by curing the synthesized polyol mixture with 1,6-diisocyanatohexance along with different amount of 1,3-propanediol (PDO) as chain extender. Tensile tests showed that yield strengths of the polyurethanes ranged from 2.74 to 27.76 MPa depending on the content of PDO. Differential scanning calorimetry analysis displayed one glass transition temperature in the range of 24.428.7 degrees C for all of the polyurethane samples, and one melt peak at high content of PDO. Thermogravimetric analysis showed that thermal degradations of the polyurethanes started at 240255 degrees C. In consideration of simple preparation process and renewable property of ESO, the bio-based polyurethane would have wide range of applications. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 127: 1929-1936, 2013 |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | SLABSTOCK VISCOELASTIC FOAMS ; VEGETABLE-BASED POLYOLS ; SOY-BASED POLYOLS ; RENEWABLE RESOURCES ; ACID ; DERIVATIVES ; NETWORKS ; POLYMERS ; GUIDANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000310603100061 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13671]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Natl Key Lab Biochem Engn, Inst Proc Engn, Beijing, Peoples R China 2.Univ Minnesota, Dept Bioprod & Biosyst Engn, Inst Biotechnol, St Paul, MN 55108 USA |
| 推荐引用方式 GB/T 7714 | Miao, Shida,Zhang, Songping,Su, Zhiguo,et al. Synthesis of bio-based polyurethanes from epoxidized soybean oil and isopropanolamine[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2013,127(3):1929-1936. |
| APA | Miao, Shida,Zhang, Songping,Su, Zhiguo,&Wang, Ping.(2013).Synthesis of bio-based polyurethanes from epoxidized soybean oil and isopropanolamine.JOURNAL OF APPLIED POLYMER SCIENCE,127(3),1929-1936. |
| MLA | Miao, Shida,et al."Synthesis of bio-based polyurethanes from epoxidized soybean oil and isopropanolamine".JOURNAL OF APPLIED POLYMER SCIENCE 127.3(2013):1929-1936. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。