Convenient synthesis of (o-CF3Ph)(2)PS2H and evaluation in selective extraction of actinides over lanthanides
文献类型：期刊论文
| 作者 | Wang, Fang1; Jia, Cai2; Chen, Jing1 |
| 刊名 | JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
 |
| 出版日期 | 2013-10-01 |
| 卷号 | 298期号:1页码:531-536 |
| 关键词 | Dithiophosphinic acids Synthesis Actinides Lanthanides Separation |
| 英文摘要 | A convenient method was established for the synthesis of bis(ortho-trifluoromethylphenyl) dithiophosphinic acid (o-CF3Ph)(2)PS2H. The three-step route consisted of reactions of PCl3 with Grignard's reagent, sulphur and NaHS in turn in liquid phase. The title compound was purified through the formation of ammonium salt (o-CF3Ph)(2)PS2NH4 and characterized with NMR and HRMS. Both chemical and radiation stability of title compound were examined. The investigation on selective extraction of Am3+ over Eu3+ was carried out from weak acidic aqueous phase with traces amount of radioactive elements Am-241 and Eu-152,Eu-154. (o-CF3Ph)(2)PS2H in toluene afforded excellent Am3+ extraction ability, with distribution ratio up to around 150, meanwhile the excellent actinides selectivity was obtained. Such performance indicated the potential application of (o-CF3Ph)(2)PS2H in selective actinides extraction over lanthanides. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Analytical ; Chemistry, Inorganic & Nuclear ; Nuclear Science & Technology |
| 研究领域[WOS] | Chemistry ; Nuclear Science & Technology |
| 关键词[WOS] | DITHIOPHOSPHINIC ACIDS ; DIALKYLDITHIOPHOSPHINIC ACID ; TRIVALENT ACTINIDES ; SEPARATION ; COMPLEXES ; AM(III) ; CHEMISTRY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000324546100068 |
| 公开日期 | 2015-05-27 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13691]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Fang,Jia, Cai,Chen, Jing. Convenient synthesis of (o-CF3Ph)(2)PS2H and evaluation in selective extraction of actinides over lanthanides[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2013,298(1):531-536. |
| APA | Wang, Fang,Jia, Cai,&Chen, Jing.(2013).Convenient synthesis of (o-CF3Ph)(2)PS2H and evaluation in selective extraction of actinides over lanthanides.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,298(1),531-536. |
| MLA | Wang, Fang,et al."Convenient synthesis of (o-CF3Ph)(2)PS2H and evaluation in selective extraction of actinides over lanthanides".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 298.1(2013):531-536. |
入库方式： OAI收割
来源：过程工程研究所
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