中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of a Homopolymer of Oligo(p-phenyleneethynylene) Attached to Alternate Carbons of a Main Chain Polyethylene and Its Liquid-Crystalline and Optical Properties

文献类型:期刊论文

作者Wang, Wen-Zhong1; Huang, Peng-Cheng2
刊名JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
出版日期2013-04-01
卷号52期号:5页码:701-715
关键词aggregates excimers light-emitting materials liquid crystalline oligo(p-phenyleneethynylene photoluminescence
英文摘要A homopolymer of oligo(p-phenyleneethynylene)s OPE-attached polyethylene (OPE-PE) was prepared through the thermal addition polymerization of the vinyls in a synthesized mono-vinyl end-capped OPE. The liquid-crystalline and optical properties of the synthesized homopolymer of OPE-PE were studied using polarizing optical microscopy (POM), wide-angle X-ray diffraction (WAXD), ultraviolet-visible (UV-vis) absorption, photoluminescence excitation (PLE) and photoluminescence (PL). The results show that the arrangements of the rigid side chains in the homopolymer of OPE-PE are affected by the flexible main chains in both liquid and solid states. Through a suitable treatment of the film, the formation of aggregates and excimers in the solid state can be avoided. This result provides a new method to eliminate the formation of aggregates and excimers in the active layers of organic light-emitting diodes (OLED) devices, and this kind of homopolymer with OPE side chains could be a promising class of light-emitting materials.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]SOLID-STATE ; SIDE-CHAIN ; POLYMERS ; POLY(P-PHENYLENEETHYNYLENE)S ; POLY(ARYLENEETHYNYLENE)S ; AGGREGATION ; ROD
收录类别SCI
语种英语
WOS记录号WOS:000319376200005
公开日期2015-05-27
源URL[http://ir.ipe.ac.cn/handle/122111/13700]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
2.Beihang Univ, Sch Mat Sci & Engn, Dept Polymer Mat & Composites, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Wang, Wen-Zhong,Huang, Peng-Cheng. Synthesis of a Homopolymer of Oligo(p-phenyleneethynylene) Attached to Alternate Carbons of a Main Chain Polyethylene and Its Liquid-Crystalline and Optical Properties[J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,2013,52(5):701-715.
APA Wang, Wen-Zhong,&Huang, Peng-Cheng.(2013).Synthesis of a Homopolymer of Oligo(p-phenyleneethynylene) Attached to Alternate Carbons of a Main Chain Polyethylene and Its Liquid-Crystalline and Optical Properties.JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,52(5),701-715.
MLA Wang, Wen-Zhong,et al."Synthesis of a Homopolymer of Oligo(p-phenyleneethynylene) Attached to Alternate Carbons of a Main Chain Polyethylene and Its Liquid-Crystalline and Optical Properties".JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS 52.5(2013):701-715.

入库方式: OAI收割

来源:过程工程研究所

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