A new class of ion-ion interaction: Z-bond
文献类型：期刊论文
| 作者 | Dong, Kun; Zhang, Suojiang1; Wang, Qian |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 58期号:3页码:495-500 |
| 关键词 | ionic liquid interaction hydrogen bond Z-bond |
| ISSN号 | 1674-7291 |
| 通讯作者 | Zhang, SJ (reprint author), Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China. |
| 英文摘要 | The hydrogen-bond interactions in ionic liquids have been simply described by the conventional hydrogen-bond model of A-Ha <-B. Coupling with the strong electrostatic force, however, hydrogen bond between the cation and anion shows particular features in the geometric, energetic, electronic, and dynamic aspects, which is inherently different from that of the conventional hydrogen bond. A general model could be expressed as (+)[A-Ha <-B](-), in which A and B represent heavy atoms and "+" and "-aEuroe represent the charges of the cation containing A atom and anion containing B atom, respectively. Because the structure shows a "zig-zag" motif, this coupling interaction is defined here as the Z-bond. The new model could be generally used to describe the interactions in ionic liquids, as well as bio-systems involved in ions, ionic reaction, and ionic materials. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HYDROGEN-BONDS ; SOLID-STATE ; LIQUIDS ; SALTS ; SPECTROSCOPY ; COMPLEXES ; CHLORIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350336500020 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/13822]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Kun,Zhang, Suojiang,Wang, Qian. A new class of ion-ion interaction: Z-bond[J]. SCIENCE CHINA-CHEMISTRY,2015,58(3):495-500. |
| APA | Dong, Kun,Zhang, Suojiang,&Wang, Qian.(2015).A new class of ion-ion interaction: Z-bond.SCIENCE CHINA-CHEMISTRY,58(3),495-500. |
| MLA | Dong, Kun,et al."A new class of ion-ion interaction: Z-bond".SCIENCE CHINA-CHEMISTRY 58.3(2015):495-500. |
入库方式： OAI收割
来源：过程工程研究所
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