中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A new class of ion-ion interaction: Z-bond

文献类型:期刊论文

作者Dong, Kun; Zhang, Suojiang1; Wang, Qian
刊名SCIENCE CHINA-CHEMISTRY
出版日期2015-03-01
卷号58期号:3页码:495-500
关键词ionic liquid interaction hydrogen bond Z-bond
ISSN号1674-7291
通讯作者Zhang, SJ (reprint author), Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China.
英文摘要The hydrogen-bond interactions in ionic liquids have been simply described by the conventional hydrogen-bond model of A-Ha <-B. Coupling with the strong electrostatic force, however, hydrogen bond between the cation and anion shows particular features in the geometric, energetic, electronic, and dynamic aspects, which is inherently different from that of the conventional hydrogen bond. A general model could be expressed as (+)[A-Ha <-B](-), in which A and B represent heavy atoms and "+" and "-aEuroe represent the charges of the cation containing A atom and anion containing B atom, respectively. Because the structure shows a "zig-zag" motif, this coupling interaction is defined here as the Z-bond. The new model could be generally used to describe the interactions in ionic liquids, as well as bio-systems involved in ions, ionic reaction, and ionic materials.
WOS标题词Science & Technology ; Physical Sciences
学科主题Chemistry
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN-BONDS ; SOLID-STATE ; LIQUIDS ; SALTS ; SPECTROSCOPY ; COMPLEXES ; CHLORIDE
收录类别SCI
语种英语
WOS记录号WOS:000350336500020
源URL[http://ir.ipe.ac.cn/handle/122111/13822]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Dong, Kun,Zhang, Suojiang,Wang, Qian. A new class of ion-ion interaction: Z-bond[J]. SCIENCE CHINA-CHEMISTRY,2015,58(3):495-500.
APA Dong, Kun,Zhang, Suojiang,&Wang, Qian.(2015).A new class of ion-ion interaction: Z-bond.SCIENCE CHINA-CHEMISTRY,58(3),495-500.
MLA Dong, Kun,et al."A new class of ion-ion interaction: Z-bond".SCIENCE CHINA-CHEMISTRY 58.3(2015):495-500.

入库方式: OAI收割

来源:过程工程研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。